Tetraanionic organoborate squares glued together by cations to generate nanotubular stacks

被引：64

作者：

Abrahams, BF ^{[1
]}

Price, DJ ^{[1
]}

Robson, R ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 05期

关键词：

boron; crystal engineering; nanotubes; spiro compounds; supramolecular chemistry;

D O I：

10.1002/anie.200503156

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Electrostatic glue: Chiral anionic molecular squares are generated by linking four spiro-biscatecholate ligands with boron centers. Through ionic interactions and hydrogen bonding, substituted ammonium ions facilitate the stacking of the anionic squares into infinite nanotubes (see picture; green B, black C, blue N, red O). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：806 / 810

页数：5

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