A lead molybdenum(V) monophosphate with a tunnel structure:: Pb3(MoO)3(PO4)5

被引：9
作者：
Leclaire, A [1 ]
Chardon, J [1 ]
Provost, J [1 ]
Raveau, B [1 ]
机构：
[1] Inst Sci Mat & Rayonnement, CNRS, UMR 6508, Lab CRISMAT, F-14050 Caen, France
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2002年 / 163卷 / 01期
关键词：
D O I：
10.1006/jssc.2001.9416
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A molybdenum(V) monophosphate containing lead has been synthesized for the first time. This new phase Pb-3(MoO)(3)(PO4)(5) crystallizes in the Pnma space group with a = 14.280(1) A, b = 15.679(1) Angstrom, and c = 8.129(1) Angstrom. The crystal structure was refined up to R = 0.0406 and R-w = 0.0446. The original three-dimensionnal framework of this compound, [Mo3P5O23]infinity, can be described by the assemblage of [Mo3P5O28]infinity ribbons running along (b) over right arrow and forming elliptic tunnels where the Pb2+ cations are located. The topological analogy of this structure with aeschynite is emphasized. The stereoactivity of the 6s(2) lone pair of Pb2+ is discussed. (C) 2002 Elsevier Science.
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页码：308 / 312
页数：5
相关论文
共 15 条
  • [1] A MOLYBDENUM(V) MONOPHOSPHATE WITH A LAYER STRUCTURE, BAMO4O8(PO4)2
    BOREL, MM
    CHARDON, J
    LECLAIRE, A
    GRANDIN, A
    RAVEAU, B
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1994, 112 (02) : 317 - 321
  • [2] Review on vanadium phosphates with mono and divalent metallic cations: syntheses, structural relationships and classification, properties
    Boudin, S
    Guesdon, A
    Leclaire, A
    Borel, MM
    [J]. INTERNATIONAL JOURNAL OF INORGANIC MATERIALS, 2000, 2 (06): : 561 - 579
  • [3] CHEN JJ, 1987, J SOLID STATE CHEM, V69, P320
  • [4] A MOLYBDENUM-V DIPHOSPHATE, BAMO2P4O16
    COSTENTIN, G
    BOREL, MM
    GRANDIN, A
    LECLAIRE, A
    RAVEAU, B
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1990, 89 (01) : 83 - 87
  • [5] COSTENTIN G, 1993, REV INORG CHEM, V13, P77
  • [6] A Mo(V) monophosphate built up from Cd2O10 and Mo2O10 bioctahedra: CdMoO2PO4
    Guesdon, A
    Leclaire, A
    Borel, MM
    Raveau, B
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1996, 122 (02) : 343 - 348
  • [7] PARALLEL, SEGREGATED CS+-FILLED AND K+-FILLED ONE-DIMENSIONAL TUNNELS IN CS2K2MO8P12O52
    HAUSHALTER, RC
    LAI, FW
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1989, 83 (01) : 202 - 206
  • [8] REDUCED MOLYBDENUM PHOSPHATES - OCTAHEDRAL TETRAHEDRAL FRAMEWORK SOLIDS WITH TUNNELS, CAGES, AND MICROPORES
    HAUSHALTER, RC
    MUNDI, LA
    [J]. CHEMISTRY OF MATERIALS, 1992, 4 (01) : 31 - 48
  • [9] CRYSTAL STRUCTURE OF ORTHORHOMBIC CATA2O6
    JAHNBERG, L
    [J]. ACTA CHEMICA SCANDINAVICA, 1963, 17 (09): : 2548 - &
  • [10] A NOVEL FORM OF MOLYBDENUM(V) PHOSPHATE - DELTA-KMO2P3O13
    LECLAIRE, A
    BOREL, MM
    GRANDIN, A
    RAVEAU, B
    [J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1989, 188 (1-2): : 77 - 83
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