Specific Chromatographic Retentions on Polymer Pore Surface of Macroporous Spongy Monoliths

被引：6

作者：

Tanigawa, Tetsuya ^{[2
]}

Kubo, Takuya ^{[3
]}

Hosoya, Ken ^{[1
]}

机构：

[1] Kyoto Prefectural Univ, Grad Sch Life & Environm Sci, Sakyo Ku, Kyoto 6068522, Japan

[2] Tohoku Univ, Grad Sch Environm Studies, Aoba Ku, Sendai, Miyagi 9808579, Japan

[3] Kyoto Univ, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan

来源：

CHEMISTRY LETTERS | 2012年 / 41卷 / 10期

关键词：

PACKING MATERIALS; COLUMN; PHASE; HPLC;

D O I：

10.1246/cl.2012.1265

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We examined chromatographic retention properties of macroporous spongy monolithic columns. Detailed chromatographic evaluations showed that planar compounds were strongly retained on poly(ethylene-co-vinyl acetate)-based monoliths, whereas sterically bulky or hydrophilic compounds were weakly retained. The comparison results with commonly used columns suggested that the specific retention abilities were a result of the differences in the polymer-chain orientation on polymer pore surface.

引用

页码：1265 / 1266

页数：2

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