Effective properties of carbon black filled natural rubber:: Experiments and modeling

被引:122
作者
Omnes, B. [1 ]
Thuillier, S. [1 ]
Pilvin, P. [1 ]
Grohens, Y. [1 ]
Gillet, S. [2 ]
机构
[1] Univ Bretagne Sud, LIMATB, F-56321 Lorient, France
[2] Soc Polymeres Barre Thomas SA, F-35043 Rennes, France
关键词
natural rubber; carbon black; reinforcement effect; elastic moduli;
D O I
10.1016/j.compositesa.2008.04.003
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Anti-vibrating parts in automotives are often made of natural rubber reinforced by carbon black. This reinforcement, which comes from the filler-filler and filler-rubber interactions, leads to an increase of the elastic modulus, the tensile strength and the hysteresis. The aim of this work is to develop a model within a generalized self-consistent scheme for filled rubber to predict the elastic moduli. A morphological pattern, which takes into account the occluded rubber, the bound rubber and a percolating network, is proposed and the effective elastic properties are compared with experimental results obtained in both uniaxial and oedometric compression. The filler volume fraction varies in-between 0% and 18% and the influence of the specific surface of the filler is investigated, by using N330 and N650 carbon blacks. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1141 / 1149
页数:9
相关论文
共 35 条
[1]   Interface effects in elastomers reinforced by modified precipitated silica [J].
Alberola, ND ;
Benzarti, K ;
Bas, C ;
Bomal, Y .
POLYMER COMPOSITES, 2001, 22 (02) :312-325
[2]  
[Anonymous], 1984, J Appl. Polym. Sci: Applym. Symp
[3]  
[Anonymous], 1962, J. Appl. Polym. Sci, V6, P368, DOI [10.1002/app.1962.070062115, DOI 10.1002/APP.1962.070062115]
[4]   Gradient of glass transition temperature in filled elastomers [J].
Berriot, J ;
Montes, H ;
Lequeux, F ;
Long, D ;
Sotta, P .
EUROPHYSICS LETTERS, 2003, 64 (01) :50-56
[5]   Evidence for the shift of the glass transition near the particles in silica-filled elastomers [J].
Berriot, J ;
Montes, H ;
Lequeux, F ;
Long, D ;
Sotta, P .
MACROMOLECULES, 2002, 35 (26) :9756-9762
[6]   Filler-elastomer interaction in model filled rubbers, a 1H NMR study [J].
Berriot, J ;
Lequeux, F ;
Monnerie, L ;
Montes, H ;
Long, D ;
Sotta, P .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2002, 307 :719-724
[7]   Reinforcement of model filled elastomers: experimental and theoretical approach of swelling properties [J].
Berriot, J ;
Lequeux, F ;
Montes, H ;
Pernot, H .
POLYMER, 2002, 43 (23) :6131-6138
[8]   Vulcanization of cis- and trans-polyisoprene and their blends:: cure characteristics and crosslink distribution [J].
Boochathum, P ;
Prajudtake, W .
EUROPEAN POLYMER JOURNAL, 2001, 37 (03) :417-427
[9]   Non-linear viscoelastic behaviour and modulus recovery in silica filled polymers [J].
Cassagnau, P ;
Mélis, F .
POLYMER, 2003, 44 (21) :6607-6615
[10]  
CHRISTENSEN RM, 1979, J MECH PHYS SOLIDS, V27, P315, DOI 10.1016/0022-5096(79)90032-2