Optimization of alkali-extrusion pretreatment with twin-screw for bioethanol production from Miscanthus

被引:52
作者
Kang, Kyeong Eop [1 ]
Han, Minhee [1 ]
Moon, Se-Kwon [1 ]
Kang, Hyun-Woo [1 ]
Kim, Yule [1 ]
Cha, Young-Lok [2 ]
Choi, Gi-Wook [1 ]
机构
[1] Changhae Ethanol Co Ltd, Changhae Adv Inst Technol, Jeonju 561203, South Korea
[2] RDA, Bioenergy Crop Res Ctr, NICS, Muan 534833, Jeonnam, South Korea
关键词
Miscanthus; Bioethanol; Twin-screw extruder; Pretreatment; Simultaneous saccharification and fermentation; ENZYMATIC-HYDROLYSIS; CORN STOVER; SACCHARIFICATION; DELIGNIFICATION; TECHNOLOGIES; FERMENTATION; KINETICS; LIGNIN; ACID; WOOD;
D O I
10.1016/j.fuel.2013.03.026
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
This study investigated the production of bioethanol from Miscanthus using a specially designed twin-screw extruder (designated CHEMET) with sodium hydroxide. Pretreatment parameters were optimized using a response surface methodology and we evaluated the efficiency of pretreatment through the biomass to ethanol ratio (BTER). Optimum pretreatment conditions were 95 degrees C, 0.4 M sodium hydroxide concentration, 80 rpm twin-screw speed, and flow rate of 120 mL/min. Under these optimum conditions, actual BTER was 66 +/- 2%, compared with a theoretical maximum of 67 +/- 3%. Simultaneous saccharification and fermentation (SSF) was used to optimize enzyme and biomass dosage, giving a maximized ethanol concentration of 67.0 g/L and an ethanol conversion rate of 88.1% for 25% loading of pretreated Miscanthus with 30 FPU/g glucose of enzyme. The findings contribute to the development of continuous-production methods of obtaining bioethanol from lignocellulosic biomass. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:520 / 526
页数:7
相关论文
共 37 条
[1]  
Akhtar M. S., 2001, International Journal of Agriculture and Biology, V3, P199
[2]   Pretreatment technologies for an efficient bioethanol production process based on enzymatic hydrolysis: A review [J].
Alvira, P. ;
Tomas-Pejo, E. ;
Ballesteros, M. ;
Negro, M. J. .
BIORESOURCE TECHNOLOGY, 2010, 101 (13) :4851-4861
[3]  
[Anonymous], APPL MICROBIOLOGY BI
[4]  
Badger P.C., 2002, TRENDS NEW CROPS NEW
[5]   Production of bioethanol from lignocellulosic materials via the biochemical pathway: A review [J].
Balat, Mustafa .
ENERGY CONVERSION AND MANAGEMENT, 2011, 52 (02) :858-875
[6]   STEAM-EXPLOSION PRETREATMENT OF WOOD - EFFECT OF CHIP SIZE, ACID, MOISTURE-CONTENT AND PRESSURE-DROP [J].
BROWNELL, HH ;
YU, EKC ;
SADDLER, JN .
BIOTECHNOLOGY AND BIOENGINEERING, 1986, 28 (06) :792-801
[7]   KINETICS OF ENZYMATIC-HYDROLYSIS OF LIGNOCELLULOSIC MATERIALS BASED ON SURFACE-AREA OF CELLULOSE ACCESSIBLE TO ENZYME AND ENZYME ADSORPTION ON LIGNIN AND CELLULOSE [J].
CONVERSE, AO ;
OOSHIMA, H ;
BURNS, DS .
APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY, 1990, 24-5 :67-73
[8]  
Dale B. E., 1985, Developments in Industrial Microbiology, V26, P223
[9]   Hydrothermal pre-treatment of rapeseed straw [J].
Diaz, Manuel J. ;
Cara, Cristobal ;
Ruiz, Encarnacion ;
Romero, Inmaculada ;
Moya, Manuel ;
Castro, Eulogio .
BIORESOURCE TECHNOLOGY, 2010, 101 (07) :2428-2435
[10]   Effect of oxygen delignification on the rate and extent of enzymatic hydrolysis of lignocellulosic material [J].
Draude, KM ;
Kurniawan, CB ;
Duff, SJB .
BIORESOURCE TECHNOLOGY, 2001, 79 (02) :113-120