Two-dimensional cobalt-bipyridinedicarboxylate coordination polymer:: [Co(2,2′-bipyridine-5,5′-dicarboxylato)(H2O)]•(H2O)

被引:36
作者
Min, DW
Yoon, SS
Lee, SW
机构
[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea
[2] Sungkyunkwan Univ, Sch Mol Sci BK21, Suwon 440746, South Korea
关键词
2,2 '-bipyridine-5,5 '-dicarboxylic acid; two-dimensional coordination-polymer; hydrothermal reaction;
D O I
10.1016/S1387-7003(01)00366-5
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Hydrothermal reaction between cobalt(II) nitrate and 2,2'-bipyridine-5,5'-dicarboxylic acid in the presence of NaOAc gave a two-dimensional coordination-polymer of cobalt(II), [Co(2, 2'-bipyridine-5,5'-dicarboxylato)(H2O)].(H2O) (1). X-ray structure determination showed that compound 1 has a two-dimensional infinite network based on cobalt-bipyridinedicarboxylate building blocks and has a relatively small channel of 5.0 x 6.6 Angstrom. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码:143 / 146
页数:4
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