Two-dimensional cobalt-bipyridinedicarboxylate coordination polymer:: [Co(2,2′-bipyridine-5,5′-dicarboxylato)(H2O)]•(H2O)

被引：36

作者：

Min, DW

Yoon, SS

Lee, SW

机构：

[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea

[2] Sungkyunkwan Univ, Sch Mol Sci BK21, Suwon 440746, South Korea

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 02期

关键词：

2,2 '-bipyridine-5,5 '-dicarboxylic acid; two-dimensional coordination-polymer; hydrothermal reaction;

D O I：

10.1016/S1387-7003(01)00366-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrothermal reaction between cobalt(II) nitrate and 2,2'-bipyridine-5,5'-dicarboxylic acid in the presence of NaOAc gave a two-dimensional coordination-polymer of cobalt(II), [Co(2, 2'-bipyridine-5,5'-dicarboxylato)(H2O)].(H2O) (1). X-ray structure determination showed that compound 1 has a two-dimensional infinite network based on cobalt-bipyridinedicarboxylate building blocks and has a relatively small channel of 5.0 x 6.6 Angstrom. (C) 2002 Published by Elsevier Science B.V.

引用

页码：143 / 146

页数：4

共 23 条

[1] ASSEMBLY OF PORPHYRIN BUILDING-BLOCKS INTO NETWORK STRUCTURES WITH LARGE CHANNELS [J].