2D and 1D Coordination Polymers of Ag(I) Ions with 2,6-Naphthalenedicarboxylate and N-Donor Coligands

被引：8

作者：

Bera, Madhusudan ^{[1
]}

Jana, Swapan Kumar ^{[1
]}

Hazari, Debdoot ^{[1
]}

Rana, Abhinandan ^{[1
]}

Chowdhuri, Durga Sankar ^{[1
]}

Puschmann, Horst ^{[2
]}

Zangrando, Ennio ^{[3
]}

Dalai, Sudipta ^{[1
]}

机构：

[1] Vidyasagar Univ, Dept Chem & Chem Technol, Midnapore 721102, W Bengal, India

[2] Univ Durham, Dept Chem, Durham DH1 3LE, England

[3] Univ Trieste, Dipartimento Sci Chim & Farmaceut, I-34127 Trieste, Italy

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2013年 / 23卷 / 02期

关键词：

Silver(I); 2,6-Naphthalenedicarboxylicacid; 2-Methylpyrazine; Argentophilic interactions; pi-pi Stacking; Photoluminescence; CRYSTAL-STRUCTURES; LIGANDS; SILVER; COPPER(I); ADDUCTS;

D O I：

10.1007/s10904-012-9780-y

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Two new Ag(I) coordination polymers [Ag-2(mepyz)](2,6-ndc)] (n) (1) and [Ag-4(4,4'-bipy)](4)(2,6-ndc)(2)center dot 8(H2O) (2) (where 2,6-ndcH(2) = 2,6-napthalene dicarboxylic acid, mepyz = 2-methyl pyrazine and 4,4'-bipy = 4,4'-bipyridine) have been synthesized and characterized by single crystal X-ray diffraction analysis. Complex 1 displays a 2D rectangular grid architecture comprising short Ag center dot center dot center dot Ag interactions, while 2 is a 1D coordination polymer: both enlarge their dimensionality to 3D via weak interactions. Luminescence study performed on complexes as well on ligands shows metal perturbed intraligand CT transition. Two new luminescent coordination polymers of Ag(I) have been synthesized. The X-ray structural determination analysis revealed 2D and 1D coordination polymers that enlarge dimensionality to 3D via weak supramolecular interactions.

引用

页码：325 / 332

页数：8

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