Ru nanoparticles immobilized on montmorillonite by ionic liquids: A highly efficient heterogeneous catalyst for the hydrogenation of benzene

被引:191
作者
Miao, SD [1 ]
Liu, ZM [1 ]
Han, BX [1 ]
Huang, J [1 ]
Sun, ZY [1 ]
Zhang, JL [1 ]
Jiang, T [1 ]
机构
[1] Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China
关键词
clays; heterogeneous catalysis; hydrogenation; ionic liquids; ruthenium;
D O I
10.1002/anie.200502632
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) In three steps to ruthenium-based heterogeneous catalysts: The central element of this novel and simple route is the immobilization of Ru0 nanoparticles on montmorillonite (see picture; the arrows indicate a Ru nanoparticle intercalated in the interlaminar space of montmorillonite) with the help of an ionic liquid. The resulting catalyst is highly efficient for the hydrogenation of benzene. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:266 / 269
页数:4
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