Phenylborylene: Direct spectroscopic characterization in inert gas matrices

被引：56
作者：
Bettinger, HF [1 ]
机构：
[1] Ruhr Univ Bochum, Lehrstuhl Organ Chem 2, D-44780 Bochum, Germany
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 08期
关键词：
D O I：
10.1021/ja0548642
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The photolysis of bisazidophenylborane isolated in cryogenic matrices results in phenylborylene, a subvalent boron(I) species with a singlet ground state. Broad band irradiation of phenylborylene causes formation of benzoborirene by insertion into an ortho-CH bond. Copyright © 2006 American Chemical Society.
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页码：2534 / 2535
页数：2
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