Phenylborylene: Direct spectroscopic characterization in inert gas matrices

被引：56

作者：

Bettinger, HF ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Lehrstuhl Organ Chem 2, D-44780 Bochum, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 08期

关键词：

D O I：

10.1021/ja0548642

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photolysis of bisazidophenylborane isolated in cryogenic matrices results in phenylborylene, a subvalent boron(I) species with a singlet ground state. Broad band irradiation of phenylborylene causes formation of benzoborirene by insertion into an ortho-CH bond. Copyright © 2006 American Chemical Society.

引用

页码：2534 / 2535

页数：2

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