Sonochemical synthesis of a two-dimensional supramolecular polymer with nanoporous morphology, linear thallophilic and covalent hydrogen-bonding interactions

被引：11
作者：
Yusefi, Sahar [1 ]
Akhbari, Kamran [1 ]
White, Jonathan [2 ,3 ]
Phuruangrat, Anukorn [4 ]
机构：
[1] Univ Tehran, Coll Sci, Sch Chem, Tehran, Iran
[2] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia
[3] Univ Melbourne, Bio21 Inst, Melbourne, Vic 3010, Australia
[4] Prince Songkla Univ, Fac Sci, Dept Mat Sci & Technol, Hat Yai, Songkhla, Thailand
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2019年 / 33卷 / 03期
关键词：
hydrogen bonding; nano; sonochemical; thallium (I); thallophillic; METAL-ORGANIC FRAMEWORKS; TETRANUCLEAR CUBIC CAGE; THALLIUM(I) COORDINATION POLYMER; SOLID-STATE CONVERSION; ULTRASONIC IRRADIATION; COMPLEXES; FLUORESCENCE; NANO; NANOSTRUCTURES; NICKEL(II);
D O I：
10.1002/aoc.4747
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A new thallium-based supramolecular polymer [Tl(mu(3)-3-HClb)(mu(3)-3-Clb)](n) (1), (3-HClb = 3-chloroperbenzoic acid), has been synthesized and structurally characterized by single crystal X-ray crystallography. It has a two-dimensional structure with linear thallophilic and covalent hydrogen-bonding interactions. In order to evaluate the effects of concentration, ultrasonic irradiation and type of solvents on structure, morphology and thermal behavior of 1, some experiments were designed, and eight samples of 1 were synthesized under different conditions. These samples were characterized by IR spectroscopy, thermogravimetric and differential thermal analyses, X-ray powder diffraction and scanning electron microscopy.
引用
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页数：12
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共 54 条
[1]   High proton-conduction in a three-dimensional microporous coordination polymer of Mn(II) [J].
Agarwal, Rashmi A. .
INORGANIC CHEMISTRY COMMUNICATIONS, 2016, 70 :115-117
[2]   Spectroscopic, thermal, fluorescence and structural studies of new TlI pyridine dicarboxylate complexes, [Tl2(py-2,5-dc)] and [T12(py-3,5-dc)] [J].
Akhbari, Kamran ;
Morsali, Ali .
JOURNAL OF MOLECULAR STRUCTURE, 2008, 878 (1-3) :65-70
[3]   Thermal, fluorescence, structural and solution studies of a thallium(I) one-dimensional coordination polymer with 4-aminobenzoate (AB-), [T1(μ4-AB)]n [J].
Akhbari, Kamran ;
Morsali, Ali .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (23) :5141-5146
[4]   Highly polyhapto-aromatic interactions in thallium(I) coordination [J].
Akhbari, Kamran ;
Morsali, All .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (23) :5109-5112
[5]   A novel tetranuclear cubic cage, [Tl4(μ3-dcp)4] {Hdcp=2,4-dichlorophenol, new short Cl...Cl interactions, thermal, fluorescence, structural and solution studies [J].
Akhbari, Kamran ;
Morsali, Ali .
INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (10) :1189-1193
[6]   [Tl2(μ-Htdp)2(μ-H2O)]n (H2tdp=4,4′-thiodiphenol) -: A one-dimensional thallium(I) coordination polymer with a large tetranuclear metallacycle:: Thermal, emission and structural studies [J].
Akhbari, Kamran ;
Morsali, Ali ;
Hunter, Allen D. ;
Zeller, Matthias .
INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (02) :178-182
[7]   The effects of solvent and ultrasonic irradiation in synthesis of thallium(I) nano supramolecular polymers and use them as template for synthesis of thallium(III) oxide nanostructures with desirable morphology [J].
Akhbari, Kamran ;
Karami, Sepideh ;
Saedi, Zahra .
ULTRASONICS SONOCHEMISTRY, 2018, 42 :640-646
[8]   Solid-State Structural Transformations of Two AgI Supramolecular Polymorphs to Another Polymer upon Absorption of HNO3 Vapors [J].
Akhbari, Kamran ;
Morsali, Ali .
INORGANIC CHEMISTRY, 2013, 52 (06) :2787-2789
[9]   Halogen dipole moment effect of phenolic ring on formation of stair like polymers or polymers with tetranuclear cubic cage units; new precursors for preparation of TlCl and Tl2O3 nanostructures [J].
Akhbari, Kamran ;
Morsali, Ali .
CRYSTENGCOMM, 2012, 14 (05) :1618-1628
[10]   A thallium(I) tetranuclear cubic cage unit in an interpenetrated supramolecular polymer: A new precursor for the preparation of Tl2O3 nanostructures [J].
Akhbari, Kamran ;
Morsali, Ali .
POLYHEDRON, 2011, 30 (15) :2459-2465
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