Cu-Sn-S system: Vibrational properties and coexistence of the Cu2SnS3, Cu3SnS4 and Cu4SnS4 compounds

被引：16

作者：

Guc, Maxim ^{[1
]}

Oliva, Florian ^{[1
]}

Fairbrother, Andrew ^{[1
,4
]}

Jawhari, Tariq ^{[2
]}

Alcobe, Xavier ^{[2
]}

Placidi, Marcel ^{[1
]}

Perez-Rodriguez, Alejandro ^{[1
,3
]}

Saucedo, Edgardo ^{[1
]}

Izquierdo-Roca, Victor ^{[1
]}

机构：

[1] Catalonia Inst Energy Res IREC, St Adria De Besos, Spain

[2] Univ Barcelona CCiTUB, Ctr Cient & Tecnol, Barcelona, Spain

[3] Univ Barcelona, Dept Elect, IN2UB, Barcelona, Spain

[4] Ecole Polytech Fed Lausanne, Lausanne, Switzerland

来源：

SCRIPTA MATERIALIA | 2020年 / 186卷 / 186期

基金：

欧盟地平线“2020”;

关键词：

Cu-Sn-s; Raman spectroscopy; X-ray diffraction; Semiconductor compounds; Polymorphic phase transformation; THIN-FILMS; RAMAN-SCATTERING; SULFURIZATION; PRECURSORS; GROWTH; SULFUR;

D O I：

10.1016/j.scriptamat.2020.05.050

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

In the present study the transformation between Cu2SnS3, Cu3SnS4 and Cu4SnS4 compounds is analyzed by means of X-ray diffraction and Raman scattering spectroscopy. A detailed analysis of the X-ray diffractograms showed the dependence of formation of the indicated compositional phases from the [Cu]/[Sn] ratio, which was also correlated with the evolution of the Raman spectra. The results are complemented with the detailed analysis of microscopic Raman imaging. Finally, fingerprint Raman spectrum for each compositional polymorph is presented, which should exclude any misinterpretations during phase analysis in future works. (C) 2020 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

引用

页码：180 / 184

页数：5

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