A quantitative UV-VIS probe of enantioselectivity in metalloporphyrin catalyzed oxygenation using aluminium model complexes

被引：11

作者：

Collman, JP ^{[1
]}

Wang, Z ^{[1
]}

Linde, C ^{[1
]}

Fu, L ^{[1
]}

Dang, L ^{[1
]}

Brauman, JI ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 18期

关键词：

D O I：

10.1039/a904141i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

UV-VIS spectroscopy is used to study the selective binding of enantiomeric pairs of chiral epoxides to an alpha alpha beta beta binaphthyl-strapped Al porphyrin; the binding selectivity correlates to the enantioselectivity in the epoxidation of alkenes catalyzed by its Fe analog.

引用

页码：1783 / 1784

页数：2

共 17 条

[11]

Ojima I., 2010, CATALYTIC ASYMMETRIC

[12] METAL-MEDIATED ENANTIOSELECTIVE ACCESS TO UNFUNCTIONALIZED ALIPHATIC OXIRANES - PROCHIRAL AND CHIRAL RECOGNITION [J].