Two luminescent alkali-silver heterometallic sulfonates

被引：23

作者：

Li, QA ^{[1
]}

Liu, X ^{[1
]}

Fu, ML ^{[1
]}

Guo, GC ^{[1
]}

Huang, JS ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Res Lab Struct Chem, Fujian 350002, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 07期

基金：

中国国家自然科学基金;

关键词：

argentophilic interactions; crystal structures; alkali metal; luminescence;

D O I：

10.1016/j.ica.2006.01.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Systematic survey on the reactions of silver nitrate with H(3)Ssal ligand (H(3)Ssal = 5-sulfo-salicylic acid) accompanying with different alkali metal ions under alkali conditions leads to two novel luminescent alkali-silver heterometallic sulfortates, [KAg(HSsal)(H2O)3], (1) with a 3-D structure constructed by [K2O10] binuclear units linking 1-D-infinity(1)[Ag-2(HSsal)(2)] double chains, [NaAg(HSsal)(H2O)(3)](n) (2) with a 3-D structure constructed by the [Ag-2(HSsal)(2)] dimers connecting 1-D-infinity(1)[NaO6] chains, and also reveals the coordination strength of the alkali metal cations and Ag+ towards the sulfonate groups with K+ > Na+ > Ag+ > Li+ order. The two compounds show intense blue emissions in both solid state and water solution. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：2147 / 2153

页数：7

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