Synthesis of CuInS2 nanoparticles via simple microwave approach and investigation of their behavior in solar cell

被引:38
作者
Sabet, Mohammad [1 ]
Salavati-Niasari, Masoud [2 ]
Ghanbari, Davood [1 ]
Amiri, Omid [1 ]
Yousefi, Mohammad [3 ]
机构
[1] Islamic Azad Univ, Sanandaj Branch, Fac Sci, Dept Chem, Sanandaj, Iran
[2] Univ Kashan, Inst Nanosci & Nanotechnol, Kashan, Iran
[3] Islamic Azad Univ, Shahre Rey Branch, Tehran, Iran
基金
美国国家科学基金会;
关键词
CuInS2; Nanoparticles; Solar cells; Microwave; Inorganic precursor; SHAPE-CONTROLLED SYNTHESIS; OPTICAL-PROPERTIES; TERNARY; NANOCRYSTALS; CUIN(S; SE)(2);
D O I
10.1016/j.mssp.2012.12.011
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Copper indium sulfide, CuInS2, nanocrystals were synthesized by a new precursor complex, [bis(2-hyroxyacetophenato)copper(II)], [Cu(HAP)(2)], via a microwave method. The effects of sulfur sources, solvents, heating time and microwave power on morphology of product were investigated. The as-synthesized CuInS2 nanoparticles were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), ultraviolet-visible (UV-vis) spectroscopy, and room temperature photoluminescence (PL) spectroscopy. The nanoparticles of CuInS2 were used to prepare CuInS2 film by doctor's blade technique. The fill factor (FF), open circuit voltage (V-oc), and short circuit current (I-sc) were obtained by I-V characterization. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:696 / 704
页数:9
相关论文
共 46 条
[21]   Microwave-assisted synthesis and characterization of 3D flower-like Bi2S3 superstructures [J].
Lu, Juan ;
Han, Qiaofeng ;
Yang, Xujie ;
Lu, Lude ;
Wang, Xin .
MATERIALS LETTERS, 2007, 61 (14-15) :2883-2886
[22]   Synthesis of nanocrystalline CuMS2 (M = In or Ga) through a solvothermal process [J].
Lu, QY ;
Hu, JQ ;
Tang, KB ;
Qian, YT ;
Zhou, GE ;
Liu, XM .
INORGANIC CHEMISTRY, 2000, 39 (07) :1606-+
[23]   Microwave-assisted polyol synthesis of Pt/H-ZSM5 catalysts [J].
Mediavilla, Marta ;
Morales, Husley ;
Melo, Luis ;
Sifontes, Angela B. ;
Albornoz, Alberto ;
Llanos, Aura ;
Moronta, Delfin ;
Solano, Roger ;
Brito, Joaquin L. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2010, 131 (1-3) :342-349
[24]   APPLICATIONS OF MICROWAVE DIELECTRIC HEATING EFFECTS TO SYNTHETIC PROBLEMS IN CHEMISTRY [J].
MINGOS, DMP ;
BAGHURST, DR .
CHEMICAL SOCIETY REVIEWS, 1991, 20 (01) :1-47
[25]   Preparation of ultrafine chalcopyrite nanoparticles via the photochemical decomposition of molecular single-source precursors [J].
Nairn, Justin J. ;
Shapiro, Pamela J. ;
Twamley, Brendan ;
Pounds, Tyler ;
von Wandruszka, Ray ;
Fletcher, T. Rick ;
Williams, Mark ;
Wang, Chongmin ;
Norton, M. Grant .
NANO LETTERS, 2006, 6 (06) :1218-1223
[26]   Tunable photoluminescence wavelength of chalcopyrite CuInS2-based semiconductor nanocrystals synthesized in a colloidal system [J].
Nakamura, Hiroyuki ;
Kato, Wataru ;
Uehara, Masato ;
Nose, Katsuhiro ;
Omata, Takahisa ;
Otsuka-Yao-Matsuo, Shinya ;
Miyazaki, Masaya ;
Maeda, Hideaki .
CHEMISTRY OF MATERIALS, 2006, 18 (14) :3330-3335
[27]   Synthesis of Ternary CuInS2 Nanocrystals; Phase Determination by Complex Ligand Species [J].
Nose, Katsuhiro ;
Soma, Yuki ;
Omata, Takahisa ;
Otsuka-Yao-Matsuo, Shinya .
CHEMISTRY OF MATERIALS, 2009, 21 (13) :2607-2613
[28]   IN2O3/CDS/CUINS2 THIN-FILM SOLAR-CELL WITH 9.7-PERCENT EFFICIENCY [J].
OGAWA, Y ;
JAGERWALDAU, A ;
HASHIMOTO, Y ;
ITO, K .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1994, 33 (12B) :L1775-L1777
[29]  
Onose C, 2007, J OPTOELECTRON ADV M, V9, P3206
[30]   Synthesis of Cu-In-S ternary nanocrystals with tunable structure and composition [J].
Pan, Daocheng ;
An, Lijia ;
Sun, Zhongming ;
Hou, William ;
Yang, Yang ;
Yang, Zhengzhong ;
Lu, Yunfeng .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (17) :5620-+