Synthesis of CuInS2 nanoparticles via simple microwave approach and investigation of their behavior in solar cell

被引:38
作者
Sabet, Mohammad [1 ]
Salavati-Niasari, Masoud [2 ]
Ghanbari, Davood [1 ]
Amiri, Omid [1 ]
Yousefi, Mohammad [3 ]
机构
[1] Islamic Azad Univ, Sanandaj Branch, Fac Sci, Dept Chem, Sanandaj, Iran
[2] Univ Kashan, Inst Nanosci & Nanotechnol, Kashan, Iran
[3] Islamic Azad Univ, Shahre Rey Branch, Tehran, Iran
基金
美国国家科学基金会;
关键词
CuInS2; Nanoparticles; Solar cells; Microwave; Inorganic precursor; SHAPE-CONTROLLED SYNTHESIS; OPTICAL-PROPERTIES; TERNARY; NANOCRYSTALS; CUIN(S; SE)(2);
D O I
10.1016/j.mssp.2012.12.011
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Copper indium sulfide, CuInS2, nanocrystals were synthesized by a new precursor complex, [bis(2-hyroxyacetophenato)copper(II)], [Cu(HAP)(2)], via a microwave method. The effects of sulfur sources, solvents, heating time and microwave power on morphology of product were investigated. The as-synthesized CuInS2 nanoparticles were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), ultraviolet-visible (UV-vis) spectroscopy, and room temperature photoluminescence (PL) spectroscopy. The nanoparticles of CuInS2 were used to prepare CuInS2 film by doctor's blade technique. The fill factor (FF), open circuit voltage (V-oc), and short circuit current (I-sc) were obtained by I-V characterization. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:696 / 704
页数:9
相关论文
共 46 条
  • [11] Optical and structural characterization of copper indium disulfide thin films
    Henderson, DO
    Mu, R
    Ueda, A
    Wu, MH
    Gordon, EM
    Tung, YS
    Huang, M
    Keay, J
    Feldman, LC
    Hollingsworth, JA
    Buhro, WE
    Harris, JD
    Hepp, AF
    Raffaelle, RP
    [J]. MATERIALS & DESIGN, 2001, 22 (07): : 585 - 589
  • [12] Jenkins R., 1996, CHEM ANAL INTRO XRAY, P90
  • [13] Elemental solvothermal reaction to produce ternary semiconductor CuInE2 (E = S, Se) nanorods
    Jiang, Y
    Wu, Y
    Mo, X
    Yu, WC
    Xie, Y
    Qian, YT
    [J]. INORGANIC CHEMISTRY, 2000, 39 (14) : 2964 - +
  • [14] Kappe C.O., 2009, PRACTICAL MICROWAVE
  • [15] Controlled microwave heating in modern organic synthesis
    Kappe, CO
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (46) : 6250 - 6284
  • [16] Growth of CuInS2 crystals by a hot-press method
    Komaki, H
    Yoshino, K
    Sato, S
    Yoneta, M
    Akaki, Y
    Ikari, T
    [J]. JOURNAL OF CRYSTAL GROWTH, 2002, 236 (1-3) : 253 - 256
  • [17] Material requirements for CIS solar cells
    Konovalov, I
    [J]. THIN SOLID FILMS, 2004, 451 : 413 - 419
  • [18] Wurtzite-Chalcopyrite Polytypism in CuInS2 Nanodisks
    Koo, Bonil
    Patel, Reken N.
    Korgel, Brian A.
    [J]. CHEMISTRY OF MATERIALS, 2009, 21 (09) : 1962 - 1966
  • [19] PREPARATION AND CHARACTERIZATION OF MN DOPED SPRAYED P-CUINS2 FILMS
    LAKSHMI, RPV
    VENUGOPAL, R
    REDDY, DR
    REDDY, BK
    [J]. SOLID STATE COMMUNICATIONS, 1992, 82 (12) : 997 - 1000
  • [20] Lazarev V.B., 1993, METALLURGIYA, P240