Solubility Data for the Quaternary KOH-K3VO4-K2CrO4-H2O System at (40 and 80) °C

被引:1
|
作者
Feng, Man [1 ,2 ]
Du, Hao [1 ]
Zheng, Shili [1 ]
Wang, Shaona [1 ]
Zhang, Yi [1 ]
机构
[1] Chinese Acad Sci, Natl Engn Lab Hydromet Cleaner Prod Technol, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
VANADIUM;
D O I
10.1021/je400051n
中图分类号
O414.1 [热力学];
学科分类号
摘要
The separation of K3VO4 and K2CrO4 plays an important role in the vanadium cleaner production process using concentrated alkaline solution as reaction media. Equilibrium solubility data for the KOH-K3VO4-K2CrO4-H2O system at (40 and 80) degrees C therefore were measured and compared with ternary KOH-K3VO4-H2O and KOH-K2CrO4-H2O subsystems, respectively. Based on the data, a strategy for effective separation of K3VO4 and K2CrO4 from the KOH-K3VO4-K2CrO4-H2O system has been proposed.
引用
收藏
页码:1029 / 1033
页数:5
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