Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co2[μ-O2P(H)Mes]2(bpy)4}Br2

被引：6

作者：

Trofimova, Ekaterina A. ^{[1
]}

Dobrynin, Alexey B. ^{[1
]}

Gerasimova, Tatiana P. ^{[1
]}

Katsyuba, Sergey A. ^{[1
]}

Sinyashina, Oleg G. ^{[1
]}

Yakhvarov, Dmitry G. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Kazan Sci Ctr, AE Arbuzov Inst Organ & Phys Chem, Kazan 420088, Russia

[2] Kazan Volga Reg Fed Univ, AM Butlerov Inst Chem, Kazan 420008, Russia

来源：

MENDELEEV COMMUNICATIONS | 2013年 / 23卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; COORDINATION NETWORKS; DESIGN; STATE;

D O I：

10.1016/j.mencom.2013.05.004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of cobalt dibromide hexahydrate with 2,2'-bipyridine (bpy) and mesitylphosphinic acid MesP(O)(OH)H (Mes = = 2,4,6-trimethylphenyl) under solvothermal synthesis conditions leads to a new dinuclear cobalt(n) complex {Co-2[mu-O2P(H)Mes](2)(bpy)(4)]Br-2 formed by two bridging [mu-O2P(H)Mes}(-) ligands. X-ray crystal structure analysis of the complex displayed that cobalt ions have distorted octahedral coordination and are doubly bridged by two mesitylphosphinato ligands.

引用

页码：135 / 136

页数：2

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