Exploitation of Guest Accessible Aliphatic Amine Functionality of a Metal-Organic Framework for Selective Detection of 2,4,6-Trinitrophenol (TNP) in Water

被引：133
作者：
Mukherjee, Soumya [1 ]
Desai, Aamod V. [1 ]
Manna, Biplab [1 ]
Inamdar, Arif I. [1 ]
Ghosh, Sujit K. [1 ]
机构：
[1] IISER, Pune 411008, Maharashtra, India
来源：
CRYSTAL GROWTH & DESIGN | 2015年 / 15卷 / 09期
关键词：
PICRIC ACID; PROTON CONDUCTION; FLUORESCENT CHEMOSENSORS; CHEMICAL SENSORS; TRACE DETECTION; EXPLOSIVES; POLYMER; STABILITY; ADSORPTION; PHASE;
D O I：
10.1021/acs.cgd.5b00902
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Highly selective and sensitive aqueous phase-detection of the well-known nitro explosive environmental pollutant 2,4,6-trinitrophenol (TNP) by a water-stable, porous luminescent metal organic framework has been reported. The presence of a guest accessible aliphatic amine functionality in the MOP channels has been strategically harnessed for serving the purpose of exclusive TNP-sensing in water even in concurrent presence of other nitro aromatic and nitro aliphatic analytes.
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收藏
页码：4627 / 4634
页数：8
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