Effect of growth parameters on single crystal diamond deposition by DC Arc Plasma Jet CVD

被引:3
作者
Hei, Lifu [1 ]
Liu, Jie [1 ]
Lu, Fanxiu [1 ]
Li, Chengming [1 ]
Song, Jianhua [1 ]
Chen, Guangchao [2 ]
机构
[1] Univ Sci & Technol Beijing, Beijing 100083, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
来源
MECHATRONICS AND INTELLIGENT MATERIALS II, PTS 1-6 | 2012年 / 490-495卷
关键词
Single crystal diamond; CVD; Morphology; Growth rate; IMPURITY BLOCKING; LARGE-AREA;
D O I
10.4028/www.scientific.net/AMR.490-495.3094
中图分类号
TP [自动化技术、计算机技术];
学科分类号
0812 ;
摘要
Homoepitaxial diamond layers were grown on commercial 3.5 x 3.5 x 1.2 mm(3) HPHT synthetic type Ib (100) single crystal diamond plates using a DC Arc Plasma Jet CVD operating at gas recycling mode. The effects of substrate temperature and CH4/H-2 ratio on the surface morphology, the growth rate and the quality of the synthesized diamond have been studied using optical microscopy and Raman spectroscopy. With no intentional nitrogen added, the growth rate up to 12.3 mu m/h has been obtained in the single crystal diamond sample deposited at 1000 degrees C with CH4/H-2=0.625%, exhibiting relatively smooth surface morphology without any growth hillocks nor non-epitaxial crystallites, and presenting the typical feature of the epitaxial step-flow growth. The full width at half maximum (FWHM) of the Raman spectra was 2.08 cm(-1), which was close to that of the natural type Ha single crystal diamond.
引用
收藏
页码:3094 / +
页数:2
相关论文
共 21 条
[1]   The control of growth parameters in the synthesis of high-quality single crystalline diamond by CVD [J].
Achard, J ;
Tallaire, A ;
Sussmann, R ;
Silva, F ;
Gicquel, A .
JOURNAL OF CRYSTAL GROWTH, 2005, 284 (3-4) :396-405
[2]   The effect of nitrogen addition during high-rate homoepitaxial growth of diamond by microwave plasma CVD [J].
Chayahara, A ;
Mokuno, Y ;
Horino, Y ;
Takasu, Y ;
Kato, H ;
Yoshikawa, H ;
Fujimori, N .
DIAMOND AND RELATED MATERIALS, 2004, 13 (11-12) :1954-1958
[3]   Growth of diamond by DC Arcjet Plasma CVD: From nano-sized poly-crystal films to millimeter-sized single crystal grain [J].
Chen, G. C. ;
Li, B. ;
Li, H. ;
Lan, H. ;
Dai, F. W. ;
Xue, Q. J. ;
Han, X. Q. ;
Hei, L. F. ;
Song, J. H. ;
Li, C. M. ;
Tang, W. Z. ;
Lu, F. X. .
DIAMOND AND RELATED MATERIALS, 2010, 19 (7-9) :1078-1084
[4]   Effects of nitrogen impurities on the CVD growth of diamond: step bunching in theory and experiment [J].
de Theije, FK ;
Schermer, JJ ;
van Enckevort, WJP .
DIAMOND AND RELATED MATERIALS, 2000, 9 (08) :1439-1449
[5]  
Field J.E., 1992, PROPERTIES NATURAL S, P474
[6]  
Gabrysch M., 2008, Electronic properties of diamond
[7]   Deposition of large area high quality diamond wafers with high growth rate by DC arc plasma jet [J].
Guo, H ;
Sun, ZL ;
He, QY ;
Du, SM ;
Wu, XB ;
Wang, ZN ;
Liu, XJ ;
Cai, YH ;
Diao, XG ;
Li, GH ;
Tang, WZ ;
Zhong, GF ;
Huang, TB ;
Liu, JM ;
Jiang, Z ;
Lu, FX .
DIAMOND AND RELATED MATERIALS, 2000, 9 (9-10) :1673-1677
[8]  
Ho SS, 2006, IND DIAMOND REV, P28
[9]   High carrier mobility in single-crystal plasma-deposited diamond [J].
Isberg, J ;
Hammersberg, J ;
Johansson, E ;
Wikström, T ;
Twitchen, DJ ;
Whitehead, AJ ;
Coe, SE ;
Scarsbrook, GA .
SCIENCE, 2002, 297 (5587) :1670-1672
[10]   A study on surface morphologies of (001) homoepitaxial diamond films [J].
Lee, NS ;
Badzian, A .
DIAMOND AND RELATED MATERIALS, 1997, 6 (01) :130-145