Angular dependence of Raman spectrum for Pb(Zr,Ti)O3 epitaxial films

被引:6
|
作者
Fukushima, Hiroaki [1 ]
Ichinose, Daichi [2 ]
Funakubo, Hiroshi [2 ]
Uchida, Hiroshi [3 ]
Shima, Hiromi [1 ]
Nishida, Ken [1 ]
机构
[1] Natl Def Acad, Dept Commun Engn, Yokosuka, Kanagawa 2398686, Japan
[2] Tokyo Inst Technol, Dept Innovat & Engn Mat, Yokohama, Kanagawa 2268502, Japan
[3] Sophia Univ, Dept Mat & Life Sci, Chiyoda Ku, Tokyo 1028554, Japan
关键词
LEAD-ZIRCONATE-TITANATE; CRYSTAL ORIENTATION DEPENDENCE; MORPHOTROPIC PHASE-BOUNDARY; THIN-FILMS; PIEZOELECTRIC PROPERTIES; SINGLE-CRYSTAL; SPECTROSCOPY; MODES; SCATTERING; SYMMETRY;
D O I
10.7567/JJAP.55.10TC07
中图分类号
O59 [应用物理学];
学科分类号
摘要
Herein, we investigate the angular dependence of the Raman spectra of (001)/(100)-oriented tetragonal and (111)/(111)-oriented rhombohedral epitaxial lead zirconate titanate (PZT) films. The A(1) and E modes have the same angular dependence for the (111)/(111)-oriented rhombohedral epitaxial PZT film, but not for the (001)/(100)-oriented tetragonal epitaxial PZT film. These results agree well with theoretical predictions. On the basis of the fact that the angular dependence of the phonon mode in PZT films is linked to the crystal orientation and structure, the angular dependence of the Raman modes can be used to investigate the orientation and structure of PZT films. (C) 2016 The Japan Society of Applied Physics
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页数:5
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