Organocatalytic α-Allylation of α-Branched Aldehydes by Synergistic Catalysis of Bronsted Acids and Amines

被引：3
|
作者：
Stanek, Filip [1 ]
Stodulski, Maciej [1 ]
机构：
[1] Polish Acad Sci, Inst Organ Chem, Kasprzaka 44-52, PL-01224 Warsaw, Poland
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 2016卷 / 28期
关键词：
Organocatalysis; Synergistic catalysis; Bronsted acids; Allylation; Allylic compounds; TRANSITION-METAL CATALYSIS; ALLYLIC ALCOHOLS; NUCLEOPHILIC-SUBSTITUTION; ALKYLATION; COMBINATION; PALLADIUM; COMPLEX; SYSTEM;
D O I：
10.1002/ejoc.201600725
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Herein, we describe the first, fully organocatalytic Tsuji-Trost-type direct alpha-allylation of alpha-branched aldehydes by the combined use of N-triflyl amides and secondary amines. Aliphatic, aromatic aldehydes as well as allyl alcohols are converted into the corresponding alpha-allylated products in moderate to high yields.
引用
收藏
页码：4768 / 4772
页数：5
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