Influence of Nitrogen-Doped Carbon Quantum Dots on the Electrocatalytic Performance of the CoP Nanoflower Catalyst for OER

被引:17
作者
Wu, Shuang [1 ]
Wang, Xinyu [1 ]
Bai, Jianliang [1 ]
Zhu, Yaqing [1 ]
Yu, Xu [1 ]
Qin, Fu [1 ]
He, Pinyi [1 ]
Ren, Lili [1 ]
机构
[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China
关键词
HYDROGEN EVOLUTION REACTION; BIFUNCTIONAL ELECTROCATALYST; OXYGEN EVOLUTION; HIGHLY EFFICIENT; NANOSHEET ARRAYS; WATER; GRAPHENE; NANOCRYSTALS; REDUCTION; EMISSION;
D O I
10.1021/acs.langmuir.2c01225
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cobalt phosphides modified by nitrogen-doped carbon quantum dots (CoP-NCQDs) were successfully constructed by a facile and low-cost hydrothermal treatment, which is expected to replace traditional noble-metal oxygen evolution reaction electrode materials. Detailed experiments and findings show that nitrogen-doped carbon quantum dots (NCQDs) have a significant impact on the morphology of the CoP catalyst, and nitrogen doping can regulate the surface-active sites to obtain the catalyst with abundant structural defects. Simultaneously, nitrogen doping can regulate the content of pyridinic N and pyrrolic N, which exerts positive effects on the formation of the bond structure and electron conduction between NCQDs and CoP.
引用
收藏
页码:11210 / 11218
页数:9
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