Tervalent lanthanide and actinide ions in solution

被引：0

作者：

Ionova, GV ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Phys Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2002年 / 47卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Topical theoretical points of the solution chemistry of tervalent lanthanides and actinides related to their solvent extraction separation are concerned: a comparison is made between the properties of lanthanide and actinide aqua ions such as coordination numbers, interatomic distances, redox potentials, polarizability, and thermodynamic parameters, In-series variations in the hard-acid character of the tervalent lanthanides and actinides and the spectral properties of their complexes are discussed. The hardness of the p-, d-, and f-block elements is studied.

引用

页码：529 / 543

页数：15

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