Post-assembly polymerization of discrete organoplatinum(II) metallacycles via dimerization of coumarin pendants

被引：8

作者：

Zhang, Dengqing ^{[1
]}

Li, Dengke ^{[1
]}

Li, Xiaopeng ^{[2
]}

Jin, Wusong ^{[1
]}

机构：

[1] Donghua Univ, Coll Chem Chem Engn & Biotechnol, 2999 North Renmin Rd, Shanghai 201620, Peoples R China

[2] Univ S Florida, Dept Chem, 4202 East Fowler Ave, Tampa, FL 33620 USA

来源：

DYES AND PIGMENTS | 2018年 / 152卷

基金：

中国国家自然科学基金;

关键词：

Post-assembly; Coordination-driven self-assembly; Supramolecular polymer; Photodimerization; Coumarin; DICARBENE-DERIVED METALLACYCLES; POSTSYNTHETIC MODIFICATION; PHOTOPHYSICAL PROPERTIES; FLUORESCENCE; CONSTRUCTION; METALLACAGES; COMPLEXES; POLYMERS; HOST;

D O I：

10.1016/j.dyepig.2018.01.025

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The post-assembly modification provides a powerful strategy for constructing functional polymeric materials by the selection of suitable functional groups or external stimuli. Herein, we took advantage of photodimerization of coumarins to link the pendent coumarin functional groups of hexagonal metallacycles 1 and 2 to give metallacycle-cored supramolecular polymers 1(p) and 2(p) under UV irradiation at 365 nm.

引用

页码：43 / 48

页数：6