One Monomer and One Dimer Cd(II) Complexes of 2,9-diethoxy-1,10-Phenanthroline by Two Different Crystallizing Methods: Syntheses, Structures, and Fluorescent Property

被引：1

作者：

Niu, Cao-Yuan ^{[1
]}

Dang, Yu-Li ^{[1
]}

Feng, Cao-Ling ^{[1
]}

机构：

[1] Henan Agr Univ, Coll Sci, Zhengzhou 450002, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 06期

关键词：

CdII dimmer; crystallizing methods; diethoxy-1; 10-phenanthroline; fluorescent properties; METAL-ORGANIC FRAMEWORK; LIGAND; 1,10-PHENANTHROLINE; BINDING; CU(I);

D O I：

10.1080/15533174.2012.752008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two different crystallizing methods produced different structural complexes 1 and 2 using the same metal salt and the same bidentate organic ligand, 2,9-diethoxy-1,10-phenanthroline (L), in the same solvent. They are one monomer [Cd(L)2(H2O)] [CdCl4]center dot CH3OH (1) and one dimmer [Cd2(L)2Cl4] (2). Complex 1 is a CdII complex containing one cationic part [Cd(L)2(H2O)]2+ and one anionic part [CdCl4]2. Complex 2 is a CdII dimer bridged by chloride atoms. Furthermore, fluorescent properties of these two coordination compounds have been measured.

引用

页码：773 / 778

页数：6