Regiospecific ligand oxygenation in iron complexes of a carboxylate-containing ligand mediated by a proposed Fev-oxo species

被引：49

作者：

Nielsen, A ^{[1
]}

Larsen, FB ^{[1
]}

Bond, AD ^{[1
]}

McKenzie, CJ ^{[1
]}

机构：

[1] Univ So Denmark, Dept Chem, DK-5230 Odense M, Denmark

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 10期

关键词：

hydroxylation; iron; N ligands; N oxides; peroxides;

D O I：

10.1002/anie.200502656

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Mimicked: Through biomimetic iron activation of peroxides (H2O2 or tBuOOH), the shown N4O ligands in their iron(III) complexes can be oxygenated selectively at either an aromatic carbon atom or an aliphatic nitrogen atom. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1602 / 1606

页数：5

共 33 条

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