Peculiarities of LiB3O5 crystallization from melts studied by Raman spectroscopy

被引：8

作者：

Surovtsev, N. V. ^{[1
]}

Malinovsky, V. K. ^{[1
]}

Solntsev, V. P. ^{[2
]}

Davydov, A. V. ^{[2
]}

Tsvetkov, E. G. ^{[2
]}

机构：

[1] RAS, SB, Inst Automat & Electrometry, Novosibirsk 630090, Russia

[2] RAS, SB, Inst Geol & Mineraol, Novosibirsk 630090, Russia

来源：

JOURNAL OF CRYSTAL GROWTH | 2008年 / 310卷 / 15期

关键词：

nucleation; phase diagrams; growth from melt; borates;

D O I：

10.1016/j.jcrysgro.2008.05.010

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Specific features of melting and crystallization scenarios of lithium triborate LiB3O5 (0.25Li(2)O(center dot)0.75B(2)O(3)) are studied in situ by Raman spectroscopy. It is shown that the scenario depends on thermal history of the melt. In particular, it is possible to obtain both homogeneous and chemically inhomogeneous states of the melt at a temperature above the melting point. The factors favoring homogeneous melt and crystallization are discussed. It is shown that the Raman line near 135cm(-1) demonstrates clearly the soft-mode behavior, merging with 111 cm(-1) Raman line above 400 degrees C, and indicating a weak phase transition near this temperature. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：3540 / 3544

页数：5

共 50 条

[21] Crystallization kinetics for the synthesis of hyper-structures in P2O5-ZnO-B2O3-Al2O3-TiO2 glass ceramic composite
Na, Y. H.
Kim, Y. S.
Lee, K. H.
Kim, T. H.
Jung, Y. J.
Kim, N. J.
Yim, S. H.
Ryu, B. K.
JOURNAL OF CERAMIC PROCESSING RESEARCH, 2009, 10 (02): : 230 - 234
[22] The effect of Fe contents on the local structure and crystallization behavior of SiO2-CaO-P2O5-Fe2O3 glasses
Li, Bin
Luo, Wenqin
Wang, Yongya
Zhang, Yanhui
Wu, Haiyan
JOURNAL OF MATERIALS SCIENCE, 2018, 53 (11) : 8030 - 8038
[23] Structural evolution at short and medium range distances during crystallization of a P2O5-Li2O-Al2O3-SiO2 glass
Glatz, Pauline
Comte, Monique
Montagne, Lionel
Dountert, Bertrand
Cousin, Fabrice
Cormier, Laurent
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2020, 103 (09) : 4969 - 4982
[24] Nonisothermal crystallization kinetics and stability of leucite and kalsilite from K2O-Al2O3-SiO2 glasses
Christopoulou, Georgia
Modarresifar, Farid
Allsopp, Benjamin L.
Jones, Alan H.
Bingham, Paul A.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2019, 102 (01) : 508 - 523
[25] Dual effect of ZrO2 on phase separation and crystallization in Li2O-Al2O3-SiO2-P2O5 glasses
Zhu, Lifan
Wang, Mingzhong
Xu, Yinsheng
Zhang, Xianghua
Lu, Ping
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2022, 105 (09) : 5698 - 5710
[26] The bonded interfacial layer structure of α-Al2O3 (0001)/water at different pH values studied by sum frequency vibrational spectroscopy
Sun, Shumei
Yao, Huanzhen
Pan, Jiabao
Xian, Zhenzhe
JOURNAL OF CHEMICAL PHYSICS, 2024, 161 (21)
[27] IR and Raman investigation on the structure of (100-x)[0.33B2O3-0.67ZnO]-xV2O5 glasses
Li, Huaxin
Lin, Huixing
Chen, Wei
Luo, Lan
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2006, 352 (28-29) : 3069 - 3073
[28] In vitro bioactivity and crystallization behavior of bioactive glass in the system SiO2-CaO-Al2O3-P2O5-Na2O-MgO-CaF2
Erol, Melek
CHEMICAL PAPERS, 2010, 64 (04) : 482 - 490
[29] Effect of P2O5 and Al2O3 on crystallization, structure, microstructure and properties of Li2O-MgO-Al2O3-SiO2-TiO2-ZrO2 glass ceramics
Ariane, Khalissa
Tamayo, Aitana
Chorfa, Abdellah
Rubio, Fausto
Rubio, Juan
BOLETIN DE LA SOCIEDAD ESPANOLA DE CERAMICA Y VIDRIO, 2022, 61 (02): : 146 - 159
[30] New Transparent Glass-Ceramics Based on the Crystallization of "Anti-glass" Spherulites in the Bi2O3-Nb2O5-TeO2 System
Bertrand, Anthony
Carreaud, Julie
Delaizir, Gaelle
Shimoda, Masato
Duclere, Jean-Rene
Colas, Maggy
Belleil, Michel
Comette, Julie
Hayakawa, Tomokatsu
Genevois, Cecile
Veron, Emmanuel
Allix, Mathieu
Chenu, Sebastien
Brisset, Francois
Thomas, Philippe
CRYSTAL GROWTH & DESIGN, 2015, 15 (10) : 5086 - 5096

← 1 2 3 4 5 →