Blue light-emitting OLED using new spiro[fluorene-7,9′-benzofluorene] host and dopant materials

被引:53
作者
Kim, Kyu-Sung [1 ,2 ]
Jeon, Young-Min [1 ,2 ]
Kim, Joon-Woo [3 ]
Lee, Chil-Won [3 ]
Gong, Myoung-Seon [1 ,2 ]
机构
[1] Dankook Univ, Dept Chem, Chungnam 330714, South Korea
[2] Dankook Univ, Inst Basic Sci, Chungnam 330714, South Korea
[3] OLED Team, Shihung 429848, Kyung Gi, South Korea
关键词
blue OLED; host; dopant; spiro[fluorene-7,9'-benzonuorene; color purity;
D O I
10.1016/j.orgel.2008.05.013
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A new spiro-type compound, 2-(10-biphenylanthracene)-spiro[fluorene-7,9'-benzofluorene] (BH-3B) containing anthracene moiety was prepared for the blue host material. Also new dopant materials, 2-[4'-(phenyl-4-vinylbenzeneamine)phenyl-spiro[fluorene-7, 9'-benzofluorene] (BH-3BD) and 4-[2 -naphthyl-4'(phenyl-4-vinylbenzeneamine)I pheny I (BD-1N) were successfully synthesized and a blue OLEDs were made from them. The structure of the device was as follows; ITO/DNTPD/alpha-NPD/Host:5% dopant/Alq3/Al-LiF. Among all of the devices, the device obtained from BH-3B host doped with 5% BH-3BD showed the best electroluminescence characteristics. The emission peak of EL is at 456 nm and the CIE value is (0.15,0.14). The brightness of the device is up to 5407 cd/m(2) at 10 V with the maximum EL efficiency of 3.4 cd/A. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:797 / 804
页数:8
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