Hierarchical Mesoporous Silica Fabricated from an ABC Triblock Terpolymer as a Single Template

被引：28
作者：
Li, Jheng-Guang [1 ]
Lin, Ruei-Bin [1 ]
Kuo, Shiao-Wei [1 ]
机构：
[1] Natl Sun Yat Sen Univ, Ctr Nanosci & Nanotechnol, Dept Mat & Optoelect Sci, Kaohsiung 804, Taiwan
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2012年 / 33卷 / 08期
关键词：
hierarchical structures; mesoporous materials; self-assembly; silicas; triblock copolymers; CRYSTALLINE DIBLOCK COPOLYMERS; PACKED CYLINDER STRUCTURE; TITANIA THIN-FILMS; POROUS SILICA; PHASE-BEHAVIOR; INVERSE OPAL; POROSITY; NANOSTRUCTURES; ARCHITECTURE; SEPARATION;
D O I：
10.1002/marc.201100857
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Hierarchical mesoporous silicas containing two kinds of mesoporous size are successfully synthesized using the simple evaporation-induced self-assembly (EISA) strategy. Two blocks of hydrophobic segments (PE and PCL) in the poly(ethylene-block-ethylene oxide-block-?-caprolactone) (PE-PEO-PCL) triblock copolymer are involved in the two types of mesopore after calcination, the PE segment being attributed to the face-centered cubic (fcc) morphology (spherical pores) and the PCL segment attributed to the tetragonal cylinder structure (cylindrical pores).
引用
收藏
页码：678 / 682
页数：5
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