Transition metal-free oxidation of activated alcohols to aldehydes and ketones in 1,1,1,3,3,3-hexafluoro-2-propanol

被引：13

作者：

Khaksar, Samad ^{[1
]}

Talesh, Saeed Mohammadzadeh ^{[1
]}

机构：

[1] Islamic Azad Univ, Dept Chem, Ayatollah Amoli Branch, Amol, Iran

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2012年 / 140卷

关键词：

Fluorinated alcohols; Oxidation; Sodium hypochlorite; Aldehyde; TRANSFER CATALYTIC-SYSTEMS; SELECTIVE OXIDATION; FLUORINATED ALCOHOLS; AEROBIC OXIDATION; SODIUM-HYPOCHLORITE; SECONDARY ALCOHOLS; AU CLUSTERS; EFFICIENT; SOLVENTS; OXIDANT;

D O I：

10.1016/j.jfluchem.2012.05.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A simple and convenient procedure for the oxidation of various benzylic, allylic and some aliphatic alcohols to their corresponding carbonyl compounds is described using sodium hypochlorite as the oxidant in 1,1,1,3,3,3-hexafluoro-2-propanol without use of a catalyst or any other additive. The solvent can be readily recovered from reaction products in excellent purity for direct reuse. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：95 / 98

页数：4

共 65 条

[61] Effect of Electronic Structures of Au Clusters Stabilized by Poly(N-vinyl-2-pyrrolidone) on Aerobic Oxidation Catalysis [J].

Tsunoyama, Hironori ;

Ichikuni, Nobuyuki ;

Sakurai, Hidehiro ;

Tsukuda, Tatsuya .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (20) :7086-7093

[62] Influence of the Structure of Polyfluorinated Alcohols on Bronsted Acidity/Hydrogen-Bond Donor Ability and Consequences on the Promoter Effect [J].

Vuluga, Daniela ;

Legros, Julien ;

Crousse, Benoit ;

Slawin, Alexandra M. Z. ;

Laurence, Christian ;

Nicolet, Pierre ;

Bonnet-Delpon, Daniele .

JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (04) :1126-1133

[63] Regio- and stereoselective ring-opening reactions of epoxides with indoles and pyrroles in 2,2,2-trifluoroethanol [J].

Westermaier, Martin ;

Mayr, Herbert .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (05) :1638-1647

[64] Combination of Lithium Chloride and Hexafluoroisopropanol for Friedel-Crafts Reactions [J].

Willot, Matthieu ;

Chen, JinChun ;

Zhu, Jieping .

SYNLETT, 2009, (04) :577-580

[65] An ionic liquid based on a cyclic guanidinium cation is an efficient medium for the selective oxidation of benzyl alcohols [J].

Xie, HB ;

Zhang, SB ;

Duan, HF .

TETRAHEDRON LETTERS, 2004, 45 (09) :2013-2015

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