Transition metal-free oxidation of activated alcohols to aldehydes and ketones in 1,1,1,3,3,3-hexafluoro-2-propanol

被引：13

作者：

Khaksar, Samad ^{[1
]}

Talesh, Saeed Mohammadzadeh ^{[1
]}

机构：

[1] Islamic Azad Univ, Dept Chem, Ayatollah Amoli Branch, Amol, Iran

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2012年 / 140卷

关键词：

Fluorinated alcohols; Oxidation; Sodium hypochlorite; Aldehyde; TRANSFER CATALYTIC-SYSTEMS; SELECTIVE OXIDATION; FLUORINATED ALCOHOLS; AEROBIC OXIDATION; SODIUM-HYPOCHLORITE; SECONDARY ALCOHOLS; AU CLUSTERS; EFFICIENT; SOLVENTS; OXIDANT;

D O I：

10.1016/j.jfluchem.2012.05.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A simple and convenient procedure for the oxidation of various benzylic, allylic and some aliphatic alcohols to their corresponding carbonyl compounds is described using sodium hypochlorite as the oxidant in 1,1,1,3,3,3-hexafluoro-2-propanol without use of a catalyst or any other additive. The solvent can be readily recovered from reaction products in excellent purity for direct reuse. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：95 / 98

页数：4

共 65 条

[1] SODIUM-HYPOCHLORITE AS OXIDANT IN PHASE-TRANSFER CATALYTIC-SYSTEMS .1. OXIDATION OF AROMATIC-ALDEHYDES [J].

ABRAMOVICI, S ;

NEUMANN, R ;

SASSON, Y .

JOURNAL OF MOLECULAR CATALYSIS, 1985, 29 (03) :291-297

[2] SODIUM-HYPOCHLORITE AS OXIDANT IN PHASE-TRANSFER CATALYTIC-SYSTEMS .2. OXIDATION OF AROMATIC ALCOHOLS [J].

ABRAMOVICI, S ;

NEUMANN, R ;

SASSON, Y .

JOURNAL OF MOLECULAR CATALYSIS, 1985, 29 (03) :299-303

[3]

Backvall J.-E., 2010, MODERN OXIDATION MET

[4]

Bartholomew CH, 2006, FUNDAMENTALS OF INDUSTRIAL CATALYTIC PROCESSES, 2ND EDITION, P1, DOI 10.1002/9780471730071

[5]

Begue J.-P., 2004, HDB FLUOROUS CHEM, P341

[6] Fluorinated alcohols:: A new medium for selective and clean reaction [J].

Bégué, JP ;

Bonnet-Delpon, D ;

Crousse, B .

SYNLETT, 2004, (01) :18-29

[7]

Berkessel A, 2002, ANGEW CHEM INT EDIT, V41, P4481, DOI 10.1002/1521-3773(20021202)41:23<4481::AID-ANIE4481>3.0.CO

[8]

2-7

[9] USE OF RUTHENIUM TETROXIDE AS A MULTI-PURPOSE OXIDANT [J].

BERKOWITZ, LM ;

RYLANDER, PN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 80 (24) :6682-6684

[10]

Cainelli G., 1984, Chromium Oxidants in Organic Chemistry

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