Heterogeneous Catalytic Hydrogenation of Biobased Levulinic and Succinic Acids in Aqueous Solutions

被引：117

作者：

Corbel-Demailly, Louis ^{[1
,2
]}

Bao-Khanh Ly ^{[1
]}

Doan-Pham Minh ^{[1
]}

Tapin, Benoit ^{[3
]}

Especel, Catherine ^{[3
]}

Epron, Florence ^{[3
]}

Cabiac, Amandine ^{[2
]}

Guillon, Emmanuelle ^{[2
]}

Besson, Michele ^{[1
]}

Pinel, Catherine ^{[1
]}

机构：

[1] Univ Lyon 1, UMR CNRS 5256, Inst Rech Catalyse & Environm Lyon, IRCELYON, F-69626 Villeurbanne, France

[2] IFP Energies Nouvelles, F-69390 Solaize, France

[3] Univ Poitiers, UMR CNRS 7285, Inst Chim Milieux & Mat Poitiers, IC2MP, F-86022 Poitiers, France

来源：

CHEMSUSCHEM | 2013年 / 6卷 / 12期

关键词：

biomass; carboxylic acids; diols; heterogeneous catalysis; hydrogenation; GAMMA-VALEROLACTONE; PHASE HYDROGENATION; BIOMASS; CONVERSION; 1,4-PENTANEDIOL; HYDROGENOLYSIS; 1,4-BUTANEDIOL;

D O I：

10.1002/cssc.201300608

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Supported noble-metal catalysts (Ru, Pd or Pt) and the corresponding Re-promoted catalysts exhibit a high activity for the hydrogenation of biobased carboxylic acids. Levulinic acid and succinic acid are converted into the lactones or the diols depending on the nature of the catalyst and the reaction conditions. The highest selectivity to 1,4-pentanediol of 82% is achieved at 140 degrees C in the presence of the 1.9%Ru-3.6%Re/C catalyst.

引用

页码：2388 / 2395

页数：8

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