Preparation and performance of organic-inorganic halide perovskites

被引：9

作者：

Dou, S. Y. ^{[1
]}

Yan, L. T. ^{[1
]}

Liu, Y. C. ^{[1
]}

Du, G. ^{[1
]}

Zhou, P. ^{[1
]}

机构：

[1] Beijing Jiaotong Univ, Sch Sci, Beijing 100044, Peoples R China

来源：

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS | 2013年 / 24卷 / 12期

基金：

中国国家自然科学基金;

关键词：

SENSITIZED SOLAR-CELLS; DYE;

D O I：

10.1007/s10854-013-1489-3

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

Layered organic-inorganic perovskites have potential application in solar cells because of their unique electrical and optical properties. These materials can also overcome the instability of organic sensitizers and the disorder of metal oxides. A preliminary study on the preparation of organic-inorganic halide perovskites (CH3NH3PbI (x) Cl3-x ) was conducted in this paper. The synthesis temperature and thermal stability in air were analyzed by thermogravimetric analysis and differential scanning calorimetry. The structure and morphology of the products were investigated by X-ray diffraction and scanning electron microscopy. UV-visible spectroscopy revealed that the material had good absorption within the range of 350-750 nm and can be used as the active light-absorbing layer of solar cells. Hybrid solar cells of FTO/TiO2-CH3NH3PbI (x) Cl3-x /Spiro-MeOTAD/Ag were found to have a high fill factor of 0.5 but low power conversion efficiency of 0.28 %.

引用

页码：4862 / 4867

页数：6

共 17 条

[1] Review of stability for advanced dye solar cells [J].

Asghar, Muhammad Imran ;

Miettunen, Kati ;

Halme, Janne ;

Vahermaa, Paula ;

Toivola, Minna ;

Aitola, Kerttu ;

Lund, Peter .

ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (04) :418-426

[2] Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].

Burschka, Julian ;

Pellet, Norman ;

Moon, Soo-Jin ;

Humphry-Baker, Robin ;

Gao, Peng ;

Nazeeruddin, Mohammad K. ;

Graetzel, Michael .

NATURE, 2013, 499 (7458) :316-+

[3] A NEW SILICON P-N JUNCTION PHOTOCELL FOR CONVERTING SOLAR RADIATION INTO ELECTRICAL POWER [J].

CHAPIN, DM ;

FULLER, CS ;

PEARSON, GL .

JOURNAL OF APPLIED PHYSICS, 1954, 25 (05) :676-677

[4] Electroluminescence from an organic-inorganic perovskite incorporating a quaterthiophene dye within lead halide perovskite layers [J].

Chondroudis, K ;

Mitzi, DB .

CHEMISTRY OF MATERIALS, 1999, 11 (11) :3028-3030

[5] All-solid-state dye-sensitized solar cells with high efficiency [J].

Chung, In ;

Lee, Byunghong ;

He, Jiaqing ;

Chang, Robert P. H. ;

Kanatzidis, Mercouri G. .

NATURE, 2012, 485 (7399) :486-U94

[6] Mesoscopic CH3NH3PbI3/TiO2 Heterojunction Solar Cells [J].

Etgar, Lioz ;

Gao, Peng ;

Xue, Zhaosheng ;

Peng, Qin ;

Chandiran, Aravind Kumar ;

Liu, Bin ;

Nazeeruddin, Md. K. ;

Graetzel, Michael .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (42) :17396-17399

[7] An organic infrared electroluminescent diode utilizing a phthalocyanine film [J].

Fujii, A ;

Ohmori, Y ;

Yoshino, K .

IEEE TRANSACTIONS ON ELECTRON DEVICES, 1997, 44 (08) :1204-1207

[8] Photoelectrochemical cells [J].

Grätzel, M .

NATURE, 2001, 414 (6861) :338-344

[9] 6.5% efficient perovskite quantum-dot-sensitized solar cell [J].

Im, Jeong-Hyeok ;

Lee, Chang-Ryul ;

Lee, Jin-Wook ;

Park, Sang-Won ;

Park, Nam-Gyu .

NANOSCALE, 2011, 3 (10) :4088-4093

[10] Organic-inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors [J].

Kagan, CR ;

Mitzi, DB ;

Dimitrakopoulos, CD .

SCIENCE, 1999, 286 (5441) :945-947

← 1 2 →