Cubane and dicubane complexes stabilised by sterically demanding m-terphenyl ligands

被引:8
|
作者
Gridley, Benjamin M. [1 ]
Blundell, Toby J. [1 ]
Moxey, Graeme J. [1 ]
Lewis, William [1 ]
Blake, Alexander J. [1 ]
Kays, Deborah L. [1 ]
机构
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
基金
英国工程与自然科学研究理事会;
关键词
STRUCTURAL-CHARACTERIZATION; CRYSTAL-STRUCTURES; CD-II; ZN-II; CLUSTERS; HALIDES; 2-COORDINATE; SPECTROSCOPY; PRECURSORS; SERIES;
D O I
10.1039/c3cc46384b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction between sterically demanding m-terphenyl lithiate complexes and cadmium dihalides yields unusual cubanes where changes in ligand bulk afford different formulations, in particular a rare heterodicubane structure.
引用
收藏
页码:9752 / 9754
页数:3
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