Analysis of factors governing the formation of single-stranded helical coordination polymers from a macrocyclic metalloligand and Ca2+, Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+ and Pb2+

被引：14
|
作者：
Li, Xiao-Zeng [1 ]
Hao, Peng-Peng [1 ]
Wang, Dan [1 ]
Zhu, Li-Na [1 ]
机构：
[1] Tianjin Univ, Dept Chem, Tianjin 300072, Peoples R China
来源：
CRYSTENGCOMM | 2013年 / 15卷 / 15期
关键词：
SPONTANEOUS RESOLUTION; POLYNUCLEAR COMPLEXES; LIGANDS; DESIGN; CONSTRUCTION; POLYMORPHS; CHEMISTRY;
D O I：
10.1039/c3ce40124c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The high rigidity, asymmetric exoditopic coordination mode, angular orientations of the coordination tops and good coordination adaptability of the metalloligand, the pi center dot center dot center dot pi stacking between the adjacent metalloligands in the polymeric chains and the coordination characteristics of the nodes are responsible for the formation of the eight 1D helices.
引用
收藏
页码：2800 / 2803
页数：4
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