Steric and Electronic Parameters of a Bulky yet Flexible N-Heterocyclic Carbene: 1,3-Bis(2,6-bis(1-ethylpropyl)phenyl)imidazol-2-ylidene (IPent)

被引：47

作者：

Collado, Alba ^{[1
]}

Balogh, Janos ^{[1
]}

Meiries, Sebastien ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

Falivene, Laura ^{[2
]}

Cavallo, Luigi ^{[2
,3
]}

Nolan, Steven P. ^{[1
]}

机构：

[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] Univ Salerno, Dipartimento Chim & Biol, I-84084 Fisciano, SA, Italy

[3] KAUST, Catalysis Ctr, Thuwal 239556900, Saudi Arabia

来源：

ORGANOMETALLICS | 2013年 / 32卷 / 11期

基金：

英国工程与自然科学研究理事会;

关键词：

ORTHO-SUBSTITUTED BIARYLS; RESTRICTED FLEXIBILITY; EFFECTIVE CATALYST; PRE-CATALYST; NHC; LIGANDS; COMPLEXES; PD-PEPPSI-IPENT(CL); ASTERISK;

D O I：

10.1021/om400168b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The free N-heterocyclic carbene IPent (1; IPent = 1,3-bis(2,6-bis(1-ethylpropyl)phenyl)imidazol-2-ylidene) was prepared from the corresponding imidazolium chloride salt (2). The steric and electronic parameters of 1 were determined by synthesis of the gold(I) chloride complex [Au(IPent)Cl] (3) and the nickel-carbonyl complex [Ni(IPent)(CO)(3)] (4), respectively. 3 and 4 were fully characterized by NMR spectroscopy, elemental analysis, and X-ray diffraction studies on single crystals.

引用

页码：3249 / 3252

页数：4

共 34 条

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