Ultrafast proton transport in water-methanol mixtures

被引：1
|
作者：
Ekimova, Maria [1 ]
Hoffmann, Felix [2 ]
Bekcioglu-Neff, Guel [2 ]
Rafferty, Aidan [1 ]
Nibbering, Erik T. J. [1 ]
Sebastiani, Daniel [2 ]
机构：
[1] Max Born Inst Nichtlineare Opt & Kurzzeitspe, D-12489 Berlin, Germany
[2] Martin Luther Univ Halle Wittenberg, Inst Chem, D-06120 Halle, Saale, Germany
来源：
XXI INTERNATIONAL CONFERENCE ON ULTRAFAST PHENOMENA 2018 (UP 2018) | 2019年 / 205卷
关键词：
D O I：
10.1051/epjconf/201920509004
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Femtosecond UV/IR pump-probe experiments and ab initio molecular dynamics simulations of 7-hydroxyquinoline in water-methanol mixtures demonstrate an unexpectedly dominant OH-/CH3O- transport pathway but consistent with a solvent-dependent photoacidity free energy-reactivity correlation behaviour.
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页数：3
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