Synthesis of Heterogeneous Copper Catalyst Based on Amino-Functionalized Triazine Rings Supported by Silica-Gel for Oxidation of Alcohols

被引:5
作者
Kolahdoozan, Majid [1 ,2 ]
Kalbasi, Roozbeh Javad [1 ]
Hossaini, Mahshid [1 ]
机构
[1] Islamic Azad Univ, Shahreza Branch, Dept Chem, Esfahan 86145, Iran
[2] Islamic Azad Univ, Shahreza Branch, Young Researcher Club, Esfahan 86145, Iran
关键词
SELECTIVE OXIDATION; COVALENT ATTACHMENT; CYANURIC CHLORIDE; EPOXY-RESIN; EFFICIENT; COMPLEXES; EPOXIDATION; ALDEHYDES; SOLVENT; KETONES;
D O I
10.1155/2013/749723
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Amino-functionalized triazine supported on silica-gel was prepared. This new triazine derivate was applied as a coordinating agent for copper (II) and was characterized by different methods. The copper (II) content of the material was determined by atomic absorption. This novel transition metal supported on heterogeneous surface was used as an effective catalyst for oxidation of benzylic alcohols in the presence of H2O2. This catalyst can be reused without any significant loss of activity.
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页数:7
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共 21 条
[1]   Heterogeneous catalysis in the liquid phase oxidation of alcohols by Cu(II) complexes immobilized between silicate layers of bentonite [J].
Alizadeh, M ;
Farzaneh, F ;
Ghandi, M .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 194 (1-2) :283-287
[2]   Recent applications of 2,4,6-trichloro-1,3,5-triazine and its derivatives in organic synthesis [J].
Blotny, Grzegorz .
TETRAHEDRON, 2006, 62 (41) :9507-9522
[3]   Pd(II)-biquinoline catalyzed aerobic oxidation of alcohols in water [J].
Buffin, BP ;
Clarkson, JP ;
Belitz, NL ;
Kundu, A .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 225 (01) :111-116
[4]   A green and efficient oxidation of benzylic alcohols using H2O2 catalyzed by montmorillonite K-10 supported CoCl2 [J].
Ezabadi, Ali ;
Najafi, Ghloam Reza ;
Hashemi, Mohammad M. .
CHINESE CHEMICAL LETTERS, 2008, 19 (11) :1277-1280
[5]   Ru(III)-catalyzed oxidation of homopropargyl alcohols in ionic liquid: an efficient and green route to 1,2-allenic ketones [J].
Fan, Xuesen ;
Qu, Yingying ;
Wang, Yangyang ;
Zhang, Xinying ;
Wang, Jianji .
TETRAHEDRON LETTERS, 2010, 51 (16) :2123-2126
[6]   Cyanuric chloride: an efficient reagent for the Lossen rearrangement [J].
Hamon, Florian ;
Prie, Gildas ;
Lecornue, Frederic ;
Papot, Sebastien .
TETRAHEDRON LETTERS, 2009, 50 (49) :6800-6802
[7]   Pyridinium chlorochromate catalyzed oxidation of alcohols to aldehydes and ketones with periodic acid [J].
Hunsen, M .
TETRAHEDRON LETTERS, 2005, 46 (10) :1651-1653
[8]   Highly efficient and selective oxidation of secondary alcohols to ketones under organic solvent and transition metal free conditions [J].
Jain, Suman L. ;
Sharma, Vishal B. ;
Sain, Bir .
TETRAHEDRON, 2006, 62 (29) :6841-6847
[9]   Direct immobilisation versus covalent attachment of a Mn(III)salen complex onto an A1-pillared clay and influence in the catalytic epoxidation of styrene [J].
Kuzniarska-Biernacka, Iwona ;
Silva, Ana R. ;
Carvalho, Ana P. ;
Pires, Joao ;
Freire, Cristina .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 278 (1-2) :82-91
[10]   Molecular sieve promoted copper catalyzed aerobic oxidation of alcohols to corresponding aldehydes or ketones [J].
Liu Lin ;
Ma Juanjuan ;
Ji Liuyan ;
Wei Yunyang .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 291 (1-2) :1-4