A novel 3D Co(II) coordination polymer with a considerable 2D channel: Synthesis, topological structure, magnetic and electrochemical properties

被引：16

作者：

Cao, Jing

Shang, Ke-Xia

Deng, Wen-Ting

Liu, Jia-Cheng ^{[1
]}

机构：

[1] Northwest Normal Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Ecoenvironm Related Polymer Mat, Lanzhou 730070, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 29卷

基金：

中国国家自然科学基金;

关键词：

Co(II) complex; Topology; 3,5-Bis(hydroxymethyl)-1,2,4-triazole; Magnetic and electrochemical properties; CRYSTAL-STRUCTURE; SINGLE-CRYSTAL; MOFS; COMPLEXES; FRAMEWORK; LIGANDS;

D O I：

10.1016/j.inoche.2012.12.034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel 3D Co(II) complex [Co(Hhmt)(H2O)center dot H2O] (1) (H(3)hmt = 3,5-bis (hydroxymethyl)-1,2,4-triazole) has been hydrothermally synthesized. X-ray single crystal diffraction experiment reveals that each Hhmt(2-) ligand connects three Co(II) ions to form a 3D lvt topological framework with the (4(2).8(4)) point symbol, especially for the existence of a considerable 2D channel. The magnetic and electrochemical properties of 1 are also discussed. (c) 2013 Elsevier B.V. All rights reserved.

引用

页码：183 / 186

页数：4

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