A novel 3D Co(II) coordination polymer with a considerable 2D channel: Synthesis, topological structure, magnetic and electrochemical properties

被引：16
|
作者：
Cao, Jing
Shang, Ke-Xia
Deng, Wen-Ting
Liu, Jia-Cheng [1 ]
机构：
[1] Northwest Normal Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Ecoenvironm Related Polymer Mat, Lanzhou 730070, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 29卷
基金：
中国国家自然科学基金;
关键词：
Co(II) complex; Topology; 3,5-Bis(hydroxymethyl)-1,2,4-triazole; Magnetic and electrochemical properties; CRYSTAL-STRUCTURE; SINGLE-CRYSTAL; MOFS; COMPLEXES; FRAMEWORK; LIGANDS;
D O I：
10.1016/j.inoche.2012.12.034
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel 3D Co(II) complex [Co(Hhmt)(H2O)center dot H2O] (1) (H(3)hmt = 3,5-bis (hydroxymethyl)-1,2,4-triazole) has been hydrothermally synthesized. X-ray single crystal diffraction experiment reveals that each Hhmt(2-) ligand connects three Co(II) ions to form a 3D lvt topological framework with the (4(2).8(4)) point symbol, especially for the existence of a considerable 2D channel. The magnetic and electrochemical properties of 1 are also discussed. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：183 / 186
页数：4
相关论文
共 50 条
  • [1] Synthesis, structure and fluorescence properties of a novel 3D Sr(II) coordination polymer
    Tan, Yu-Hui
    Xu, Qing
    Gu, Zhi-Feng
    Gao, Ji-Xing
    Wang, Bin
    Liu, Yi
    Yang, Chang-Shan
    Tang, Yun-Zhi
    JOURNAL OF MOLECULAR STRUCTURE, 2016, 1119 : 346 - 350
  • [2] A 3D interpenetrated Co(II)-glutarate coordination polymer: Synthesis, crystal structure, magnetic and adsorption properties
    Teixeira, Filipe J.
    Flores, Leona S.
    Escobar, Livia B. L.
    dos Santos, Thiago C.
    Yoshida, Maria, I
    Reis, Mario S.
    Hill, Stephen
    Ronconi, Celia M.
    Correa, Charlane C.
    INORGANICA CHIMICA ACTA, 2020, 511
  • [3] A manganese(II) coordination polymer with a 3D porous structure: Synthesis, structure, and spectroscopic and magnetic behaviour
    Castineiras, Alfonso
    Garcia-Santos, Isabel
    Varela, Jose M.
    POLYHEDRON, 2009, 28 (04) : 860 - 864
  • [4] Ni(II) Coordination Polymer with 3D Supramolecular Structure
    Kong, Chunyan
    ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (02) : 927 - 928
  • [5] HYDROTHERMAL SYNTHESIS, CRYSTAL STRUCTURE AND ELECTROCHEMICAL BEHAVIOR OF 2D HYBRID COORDINATION POLYMER
    Fan, Weiqiang
    Zhu, Lin
    Shi, Weidong
    Chen, Fuxiao
    Bai, Hongye
    Song, Shuyan
    Yan, Yongsheng
    FUNCTIONAL MATERIALS LETTERS, 2013, 6 (03)
  • [6] A 2D Cobalt(II) Coordination Polymer [Co(iqnc)2]n: Synthesis, Crystal Structure and Characterizations
    Fan Guang
    Guo Jin-Chan
    Li Xiao-Bo
    Ma Zhan-Ying
    Deng Ling-Juan
    Zhang Yin-Li
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34 (10) : 1612 - 1616
  • [7] A Novel 3D Coordination Polymer Bearing Rare NbO-x-d Subnets: Synthesis, Structure, and Properties
    Wang, Tao
    Zhang, Chenxi
    Deng, Shengjun
    Liu, Yijian
    Xiao, Weiming
    Zhang, Ning
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2018, 28 (01) : 308 - 313
  • [8] New 3D dicyanamide bridged coordination polymer of Ni(II): Synthesis, crystal structure, magnetic properties and antibacterial assay
    Tabrizi, Leila
    Chiniforoshan, Hossein
    Araujo, Joao P.
    Lopes, Armandina M. L.
    Goerls, Helmar
    Plass, Winfried
    Mohammadnezhad, Gholamhossein
    INORGANICA CHIMICA ACTA, 2015, 426 : 195 - 201
  • [9] Synthesis, crystal structure and magnetic properties of 2D bi-layered coordination polymer
    Han, Zhengbo
    Li, Juan
    Gao, Jingqun
    JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (14) : 1641 - 1647
  • [10] 1D and 2D Cobalt(II) Coordination Polymers, Co(ox)(en): Synthesis, Structures and Magnetic Properties
    Kang, Jaeun
    Lee, Yumi
    Kim, Seungjoo
    Yun, Hoseop
    Do, Junghwan
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2014, 35 (11) : 3244 - 3248
12345