Structural variations in nickel, palladium, and platinum complexes containing pyrimidyl N-heterocyclic carbene ligand

被引：48

作者：

Chen, Chao ^{[1
]}

Qiu, Huayu ^{[1
]}

Chen, Wanzhi ^{[2
]}

Wang, Daqi ^{[3
]}

机构：

[1] Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Zhejiang, Peoples R China

[2] Zhejiang Univ, Dept Chem, Hangzhou 310028, Peoples R China

[3] Liaocheng Univ, Dept Chem, Liaocheng 252059, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2008年 / 693卷 / 20期

关键词：

nickel; palladium; platinium; N-heterocyclic carbene; paramagnetic;

D O I：

10.1016/j.jorganchem.2008.07.026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nickel(II), palladium(II), and platinum(II) complexes of 2-(3-mesitylimidazolylidenyl) pyrimidine (L), [Ni-2(mu-Cl)(2)(L)(4)][Ag2Cl4] (3), [Ni-2(mu-I)(2)(L)(4)][NiI(L)(2)(CH3CN)](2)[Ag4I8] (4), [PdCl2(L)] (5), [PdI2(L)] (6), and [PtCl(L)(2)][AgCl2] (7) have been obtained from the carbene transfer reactions of [Ag(L) Cl] (2). These complexes have been fully characterized by spectroscopic methods and single-crystal X-ray structure analyses. The mono(carbene) palladium and bis(carbene) platinum complexes display normal square -planar structures. Nickel complexes 3 and 4 are rare examples of paramagnetic nickel(II) complexes of N-heterocyclic carbenes having octahedral geometry. (C) 2008 Elsevier B. V. All rights reserved.

引用

页码：3273 / 3280

页数：8

共 50 条

[21] Synthesis and structural characterization of aryloxo-functionalized N-heterocyclic carbene complexes of nickel(II)
Li, WF
Sun, HM
Wang, ZG
Chen, MZ
Shen, Q
Zhang, Y
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (24-25) : 6227 - 6232
[22] Palladium complexes of a new type of N-heterocyclic carbene ligand derived from a tricyclic triazolooxazine framework
MANOJ KUMAR GANGWAR
ALOK CH KALITA
PRASENJIT GHOSH
Journal of Chemical Sciences, 2014, 126 : 1557 - 1563
[23] Synthesis and structural characterization of ruthenium(II) carbonyl complexes with a bistriazole N-heterocyclic carbene ligand
Wang, Gao-Feng
Chen, Fei
Liu, Yuan-Zhong
Chen, Xue-Tai
Xue, Zi-Ling
INORGANICA CHIMICA ACTA, 2012, 386 : 46 - 49
[24] Platinum complexes with pyrimidine-functionalized N-heterocyclic carbene ligands - Synthesis and solid state structures
Meyer, Dirk
Zeller, Alexander
Strassner, Thomas
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2012, 701 : 56 - 61
[25] Facile Hydrolysis of Nickel(II) Complexes with N-Heterocyclic Carbene Ligands
Astakhov, Alexander V.
Khazipov, Oleg V.
Degtyareva, Evgeniya S.
Khrustalev, Victor N.
Chernyshev, Victor M.
Ananikov, Valentine P.
ORGANOMETALLICS, 2015, 34 (24) : 5759 - 5766
[26] Nickel(ii) N-heterocyclic carbene complexes as efficient catalysts for the Suzuki—Miyaura reaction
S. B. Soliev
A. V. Astakhov
D. V. Pasyukov
V. M. Chernyshev
Russian Chemical Bulletin, 2020, 69 : 683 - 690
[27] Rotamers of palladium complexes bearing IR active N-heterocyclic carbene ligands: Synthesis, structural characterization and catalytic activities
Huynh, Han Vinh
Wu, Jiang
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (03) : 323 - 331
[28] Cytotoxic potential of silver, palladium, rhodium, ruthenium, and iridium complexes of a cycloheptyl-substituted lipophilic N-heterocyclic carbene ligand
Karatas, Mert Olgun
Sekerci, Guldeniz
Tekin, Suat
Sandal, Suleyman
Kucukbay, Hasan
JOURNAL OF COORDINATION CHEMISTRY, 2023, 76 (11-12) : 1507 - 1517
[29] Nanofiber composites containing N-heterocyclic carbene complexes with antimicrobial activity
Elzatahry, Ahmed A.
Al-Enizi, Abdullah M.
Elsayed, Elsayed Ahmed
Butorac, Rachel R.
Al-Deyab, Salem S.
Wadaan, Mohammad A. M.
Cowley, Alan H.
INTERNATIONAL JOURNAL OF NANOMEDICINE, 2012, 7 : 2829 - 2832
[30] New N-heterocyclic plumbylenes (NHPbs) and their complexes with palladium and platinum by DFT
Nazanin Mohebi
Mohamad Zaman Kassaee
Structural Chemistry, 2021, 32 : 731 - 757

← 1 2 3 4 5 →