Tri-functional aerogel photocatalyst with an S-scheme heterojunction for the efficient removal of dyes and antibiotic and hydrogen generation

A novel three-dimensional (3D) S-scheme S-gC(3)N(4)/TiO2/SiO2/PAN aerogel heterojunction photocatalyst (denoted as S-gTAHP) is rationally devised and manufactured by combining electrospinning, calcination, hydrothermal and freeze-drying techniques. The synthesized S-gC(3)N(4) molecule is different from tradi-tional g-C3N4, which has a small molecular structure similar to melamine. S-gC(3)N(4) is embedded in the interwoven network structure of TiO2/PAN short fibers, and the catalytic system of the S-scheme hetero-junction is formed with SiO2 as a crosslinking agent. S-gTAHP achieves perfect tri-functional photocat-alytic capability, including remarkable hydrogen release capacity (806.7 lmol center dot h(-1)center dot g(-1)), efficient removal of three colored dyes with removal efficiencies up to 99.43% (MB, 15 min), 96.13% (RhB, 30 min) and 91.32% (MO, 40 min), and a degradation rate of the colorless antibiotic TCH reaching 84.20% in 40 min driven by simulated sunlight. Meanwhile, the effects of pH values and concentrations of contaminant solutions on the removal rates are explored, and the S-scheme mechanism of S-gTAHP strengthening photocatalytic activity is elucidated. The apparently heightened photocatalytic activities of S-gTAHP can be ascribed to the fact that the 3D hierarchical porous structure of the aerogel endows more active centers and enhanced light-harvesting capacity, and the S-scheme heterojunction supplies effective charge migrating channels, thereby affording the carriers with strong redox capability. Furthermore, S-gTAHP holds prominent reusability and is light weight. Hence, efficient and recyclable 3D aerogel photocatalysts with S-scheme heterojunctions have broad application prospects in practical sew-age treatment and energy conversion fields. (C) 2022 Elsevier Inc. All rights reserved.