Synthesis and crystal structure of a three-dimensional (3D) complex Mn(H2O)2(HNic)2 (HNic=2-hydroxynicotinic acid)

被引：0
|
作者：
Li Yu-Mei [1 ]
Che Yun-Xia [1 ]
Zheng Ji-Min [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2006年 / 25卷 / 05期
关键词：
complex; crystal structure; three-dimensional network;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title complex Mn(H2O)(2)(HNiC)(2) (C12H12MnN2O8, M-r= 367.18) crystallizes in monoclinic, space group P2(1)/c with a = 7.5735(8), b = 12.5295(13), c = 7.6466(8) angstrom. beta = 101.2790(10)degrees, Z = 2, V = 711.59(13) angstrom(3), D-c = 1.714 g/cm(3). mu(MoKa) = 0.974 mm(-1), F(000) = 374, R-1 (1255 observed reflections (I > 2 sigma(I)) = 0.0250) and wR(2) = 0.0662 (all data). In this paper, we report the complexation of Mn(II) by the bidentate ligand 2-hydroxynicotinic acid (HNic). In the crystal the Mn(II) ion exhibits a deformed octahedron structure. The title complex Mn(H2O)(2)(HNic)(2) has a three-dimensional (31)) network structure extended by hydrogen bonds, which are formed by two typical eight-membered hydrogen-bonded rings.
引用
收藏
页码：572 / 576
页数：5
相关论文
共 50 条
  • [41] Synthesis and Crystal Structure of [{Mn(IBG)(2,2′-bipy)(H2O)}•4H2O]n
    Xu Han
    Li Yi-Zhi
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (03) : 483 - 487
  • [42] Synthesis and Crystal Structure of [Zn（FcCOO）2（2,2'-bipy）(H2O)]2·H2O
    胡久荣
    梁福沛
    Chinese Journal of Structural Chemistry, 2007, (07) : 793 - 796
  • [43] Crystal structures of acid ethylenediaminetetraacetates [Cd(H2Edta)(H2O)] · 2H2O and [Mn(H2O)4][Mn(HEdta)(H2O)]2 · 4H2O
    I. N. Polyakova
    A. L. Poznyak
    V. S. Sergienko
    L. V. Stopolyanskaya
    Crystallography Reports, 2001, 46 : 40 - 45
  • [44] Synthesis and crystal structure of nitrosoruthenium aquadiammine complex, [Ru(NO)(NH3)2Cl2(H2O)]Cl·H2O
    V. A. Emel’yanov
    I. A. Baidina
    M. A. Il’in
    S. A. Gromilov
    Journal of Structural Chemistry, 2006, 47 : 380 - 382
  • [45] Synthesis and Crystal Structure of [{Mn(IBG)(2,2'-bipy)(H2O)}·4H2O]n
    徐涵
    李一志
    结构化学, 2010, 29 (03) : 483 - 487
  • [46] Synthesis and crystal structure of the complex [Sm(o-MOBA)3(phen)•H2O]2•-4H2O
    Ren Ning
    Zhang Jian-Jun
    Xu Su-Ling
    Zhang Hai-Yan
    Wang Rui-Fen
    Wang Shu-Ping
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2006, 22 (10) : 1905 - 1907
  • [47] Crystal structure of a novel complex [Co(3,3′-bpbc)(H2O)3]·H2O
    E. -J. Gao
    L. -L. Jiang
    D. Zhang
    W. Jiao
    T. -L. Liu
    Y. -J. Zhang
    G. -L. Wu
    J. Xu
    Journal of Structural Chemistry, 2013, 54 : 978 - 982
  • [48] Synthesis, Characterization and Crystal Structure of a Three-dimensional Coordination Polymer {[Cd(1,5-nds)(Him)2(H2O)]•2H2O}n
    Qian Bao-Hua
    Ma Wei-Xing
    Xu Xing-You
    Lu Lu-De
    Yang Xu-Jie
    Wang Xin
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 27 (12) : 1533 - 1537
  • [49] Synthesis,Characterization and Crystal Structure of a Three-dimensional Coordination Polymer {[Cd（1,5-nds）(Him)2（H2O）]·2H2O}n
    钱保华
    马卫兴
    许兴友
    陆路德
    杨绪杰
    汪信
    结构化学, 2008, 27 (12) : 1533 - 1537
  • [50] Synthesis and crystal structure of a novel three-dimensional complex Ni(Iz)2(Bdc)(H2O)2 (Iz = imidazole, Bdc=1,4-benzenedicarboxylate)
    Tan Xiao-Na
    Che Yun-Xia
    Zheng Ji-Min
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (07) : 818 - 822
12345