Low-Pressure Nanofiltration Hollow Fiber Membranes for Effective Fractionation of Dyes and Inorganic Salts in Textile Wastewater

In this work, novel loose nanofiltration (NF) hollow fiber membranes with ultrahigh water permeability and well-defined nanopore and surface charge characteristics were developed for effective fractionation of dyes and inorganic salts in textile wastewater treatment. The as-spun NF hollow fiber possesses a high pure water permeability (PWP) of 80 L.m(-2).h(-1).bar(-1) with a small pore size of 1.0 nm in diameter and a MWCO of 1000 Da. The surface modification by means of hyperbranched polyethylenimine (PEI) further lowers the pore diameter to 0.85 nm and MWCO to 680 Da. The membrane surface also becomes more hydrophilic and positively charged after the PEI modification. Because of the synergistic effects from size exclusion and charge repulsion, the newly developed NF hollow fibers show high permeation fluxes of 7.0-71.2 L.m(-2).h(-1) and great rejections of 95.5-99.9% to various dyes at a low operating pressure of 1 bar. At the same time, they have ultralow rejections of less than 10% to inorganic salts (i.e., Na2SO4), suggesting that more than 90% of the salts would permeate through the fibers. In addition, the two hollow fibers exhibit outstanding performance stability, low fouling tendency, and great fouling reversibility. Their fluxes can be brought back to be more than 80% of the original values by a simple physical backwash. The newly developed loose NF hollow fiber membranes may have great potential for effective fractionation and treatment of textile wastewater.