Polyethylene characterization by FTIR

被引:719
作者
Gulmine, JV
Janissek, PR
Heise, HM
Akcelrud, L
机构
[1] Univ Fed Parana, Ctr Politecn, Dept Quim, BR-81531990 Curitiba, Parana, Brazil
[2] LACTEC, Inst Tecnol Desenvolvimento, BR-81531990 Curitiba, Parana, Brazil
[3] Ctr Univ Positivo, BR-81280330 Curitiba, Parana, Brazil
[4] Inst Spectrochem & Appl Spect, D-44139 Dortmund, Germany
关键词
FTIR; attenuated total reflectance; polyethylene;
D O I
10.1016/S0142-9418(01)00124-6
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Important experimental parameters for FTIR spectra acquisition were studied: apodization, beam aperture, number of scans and spectral resolution, using polyethylene samples. The optimum conditions for the analyses were established and permitted unequivocally to identify the three most important commercially available grades: low density, high density and linear low density products (LDPE, HDPE and LLDPE respectively). (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:557 / 563
页数:7
相关论文
共 21 条
[1]   On the mechanism of low temperature glass transition in low density polyethylene films [J].
Badr, Y ;
Ali, ZI ;
Khafagy, RM .
RADIATION PHYSICS AND CHEMISTRY, 2000, 58 (01) :87-100
[2]   TRANSPOSITION TO ATTENUATED TOTAL-REFLECTION OF CLASSICAL LAWS USED IN TRANSMISSION SPECTROSCOPY - APPLICATION TO CRYSTALLINITY DETERMINATION OF POLYETHYLENE TEREPHTHALATE FILMS [J].
BELALI, R ;
VIGOUREUX, JM .
APPLIED SPECTROSCOPY, 1994, 48 (04) :465-471
[3]  
BUENO WA, 1990, MANUAL ESPECTROSCOPI, P584
[4]   THE PERFORMANCE OF LIGHT STABILIZERS IN ACCELERATED AND NATURAL WEATHERING [J].
GUGUMUS, F .
POLYMER DEGRADATION AND STABILITY, 1995, 50 (01) :101-116
[5]   Critical antioxidant concentrations in polymer oxidation - III. Application to lifetime prediction [J].
Gugumus, F .
POLYMER DEGRADATION AND STABILITY, 1998, 60 (01) :119-135
[6]  
HASLAM J, 1983, IDENTIFICATION ANAL, P748
[7]   Effect of stereoregularity on the thermo-oxidative degradation of polypropylenes [J].
Kato, M ;
Osawa, Z .
POLYMER DEGRADATION AND STABILITY, 1999, 65 (03) :457-461
[8]   KINETICS OF POLYMER CRYSTALLIZATION [J].
LONG, Y ;
SHANKS, RA ;
STACHURSKI, ZH .
PROGRESS IN POLYMER SCIENCE, 1995, 20 (04) :651-701
[9]  
MITTLEMAN ML, 1994, TRENDS POLYM SCI, V2, P391
[10]  
Musto P, 1997, J POLYM SCI POL PHYS, V35, P1055, DOI 10.1002/(SICI)1099-0488(199705)35:7<1055::AID-POLB5>3.0.CO