Vibrational analysis of metal halide complexes of 1,2,4-triazole. Part One

被引：0

作者：

Zaydoun, S ^{[1
]}

Idrissi, MS

Lorriaux-Rubbens, A

Garrigou-Lagrange, C

机构：

[1] Fac Sci, Dept Chim, Lab Spect Infrarouge, Rabat, Morocco

[2] Univ Sci & Tech Lille Flandres Artois, Lab Spectrochim Infrarouge & Raman, F-59655 Villeneuve Dascq, France

[3] Ctr Rech Paul Pascal, F-33600 Pessac, France

来源：

CANADIAN JOURNAL OF ANALYTICAL SCIENCES AND SPECTROSCOPY | 1999年 / 44卷 / 01期

关键词：

D O I：

暂无

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

1,2,4-triazole forms with transition, metal(ll) halides complexes of the general formula MX,TA and MX,TA,. A thorough vibrational analysis of these complexes and their deuterated analogs has been performed and fundamental vibrations of the ligand has been assigned. The coordination mode of triazole is proposed. The fact that the Ligand vibrations shift only slightly upon, coordination is accounted for by the existence of pi-back bonding from the metal ion to the ligand.

引用

页码：10 / 17

页数：8

共 30 条

[1] A SIMPLE RELATIONSHIP BETWEEN INFRA-RED STRETCHING FREQUENCIES AND HYDROGEN BOND DISTANCES IN CRYSTALS
BELLAMY, LJ
OWEN, AJ
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1969, A 25 (02): : 329 - &
[2] INFRARED SPECTRA OF SOME COBALT NICKEL AND COPPER COMPLEXES OF HETEROAROMATIC AMINES
BILLING, DE
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1969, 31 (01): : 137 - &
[3] 1,2,4-TRIAZOLE - VIBRATIONAL-SPECTRA, NORMAL COORDINATE CALCULATIONS, AND HYDROGEN-BONDING
BOUGEARD, D
LECALVE, N
SAINTROCH, B
NOVAK, A
[J]. JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (12) : 5152 - 5164
[4] INFRA-RED SPECTRA (3000-200 CM-1) OF METAL-ISOTHIOCYANATE COMPLEXES
CLARK, RJH
WILLIAMS, CS
[J]. SPECTROCHIMICA ACTA, 1966, 22 (06): : 1081 - &
[5] 1,2,4-TRIAZOLE COMPLEXES .5. CRYSTAL-STRUCTURE OF THE LAYERED COMPOUND POLY-BIS(THIOCYANATO-N)BIS-MU-(1,2,4-TRIAZOLE-N2,N4)COBALT(II) AND ITS ZINC(II) AND COPPER(II) ANALOGS
ENGELFRIET, DW
DENBRINKER, W
VERSCHOOR, GC
GORTER, S
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (DEC): : 2922 - 2927
[6] FERRARO JR, 1968, RIC SCI, V38, P433
[7] INFLUENCE OF PROTONATION AND COMPLEX FORMATION ON VIBRATION SPECTRA OF PYRIMIDINE
FOGLIZZO, R
NOVAK, A
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1970, A 26 (12): : 2281 - +
[8] TETRAZOLES AS LIGANDS .4. IRON(II) COMPLEXES OF MONOFUNCTIONAL TETRAZOLE LIGANDS, SHOWING HIGH-SPIN REVERSIBLE LOW-SPIN TRANSITIONS
FRANKE, PL
HAASNOOT, JG
ZUUR, AP
[J]. INORGANICA CHIMICA ACTA-ARTICLES, 1982, 59 (01): : 5 - 9
[9] THE INFRA-RED SPECTRA OF PYRIDINE COMPLEXES AND PYRIDINIUM SALTS
GILL, NS
NUTTALL, RH
SCAIFE, DE
SHARP, DWA
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1961, 18 : 79 - 87
[10] REFINEMENT OF CRYSTAL AND MOLECULAR STRUCTURE OF 1,2,4-TRIAZOLE (C2H3N3) AT LOW TEMPERATURE
GOLDSTEIN, P
LADELL, J
ABOWITZ, G
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1969, B 25 : 135 - +

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