Fluorescence Emission of Amphiphilic Copolymers Bearing Benzimidazole Groups: Stimuli-responsive Behaviors in Aqueous Solution

被引：3
|
作者：
Han, Bing [1 ]
Zhou, Nianchen [1 ]
Zhang, Wei [1 ]
Cheng, Zhenping [1 ]
Zhu, Jian [1 ]
Zhu, Xiulin [1 ]
机构：
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Jiangsu Key Lab Adv Funct Polymer Design & Applic, Suzhou 215123, Peoples R China
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2013年 / 51卷 / 20期
关键词：
fluorescence; gel permeation chromatography (GPC); reversible addition fragmentation chain transfer (RAFT); stimuli-responsive amphiphilic copolymer; AGGREGATION-INDUCED EMISSION; CRITICAL SOLUTION TEMPERATURE; FRAGMENTATION CHAIN TRANSFER; FREE-RADICAL POLYMERIZATION; ACID) BLOCK-COPOLYMERS; RAFT POLYMERIZATION; DIBLOCK COPOLYMERS; 2-CYANOPROP-2-YL; 1-DITHIONAPHTHALATE; DICYANOMETHYLENE-4H-PYRAN MOIETY; MULTIPLE MORPHOLOGIES;
D O I：
10.1002/pola.26864
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A stimuli-responsive amphiphilic copolymer poly(NIPAM(m)-b-VBNBIn), including N-isopropylacrylamide (NIPAM) as a thermoresponsive unit and 1-(4-vinyl benzyl)-2-naphthyl-benzimidazole (VBNBI) as a sensitive fluorophore unit, was designed and synthesized by reversible addition-fragmentation chain transfer polymerization. The aqueous solutions of the copolymers exhibited reversible fluorescent response to pH and temperature. In addition, the copolymers showed aggregation-induced fluorescence enhancement in THF/water mixture. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4459-4466
引用
收藏
页码：4459 / 4466
页数：8
相关论文
共 50 条
  • [41] Stepwise Conformational Transitions of Stimuli-Responsive Linear Ternary Heterografted Bottlebrush Polymers in Aqueous Solution
    Kelly, Michael T.
    Kent, Ethan W.
    Zhao, Bin
    MACROMOLECULES, 2022, 55 (05) : 1629 - 1641
  • [42] Multiple stimuli-responsive rheological behavior of a functionalized telechelic associative model polymer in aqueous solution
    Du, Zhukang
    Dong, Renfeng
    Ke, Kang
    Ren, Biye
    JOURNAL OF RHEOLOGY, 2018, 62 (05) : 1233 - 1243
  • [43] Quenching in the excited singlet state of amphiphilic copolymers with pendant carbazolylalkyl groups in aqueous solution
    Itoh, Y
    Yasue, T
    Gouki, M
    Hachimori, A
    POLYMER, 1996, 37 (24) : 5433 - 5437
  • [44] Click-formed polymer gels with aggregation-induced emission and dual stimuli-responsive behaviors
    Shi, Sheng-yu
    Zhang, Guo-ying
    CHINESE JOURNAL OF CHEMICAL PHYSICS, 2021, 34 (03) : 365 - 372
  • [45] Light and temperature dual stimuli-responsive micelles from carbamate-containing spiropyran-based amphiphilic block copolymers: Fabrication, responsiveness and controlled release behaviors
    Zhang, Ruizhen
    Min, Yuting
    Ji, Peipei
    Zhou, Guiyang
    Yin, Hong
    Qi, Dongming
    Deng, Hangjun
    Hua, Zan
    Chen, Tao
    EUROPEAN POLYMER JOURNAL, 2023, 200
  • [46] Imidazole-based solid-state fluorescence switch: Stimuli-responsive emission, mechanochromism and acidochromism
    Megha
    Kaur, Paramjit
    Singh, Kamaljit
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2024, 307
  • [47] Supramolecular Assembly Induced Emission of Thiazole Orange with Sulfobutylether β-cyclodextrin: A Stimuli-Responsive Fluorescence Sensor for Tyramine
    Khurana, Raman
    Barooah, Nilotpal
    Bhasikuttan, Achikanath C.
    Mohanty, Jyotirmayee
    CHEMPHYSCHEM, 2019, 20 (19) : 2498 - 2505
  • [48] Triblock copolymers as versatile constituents of double stimuli-responsive ionic-liquid-based aqueous biphasic systems
    Rufino, Ana F. C. S.
    Ribeiro, Sara C.
    Coutinho, Joao A. P.
    Silva, Francisca A.
    Freire, Mara G.
    SEPARATION AND PURIFICATION TECHNOLOGY, 2023, 317
  • [49] One-Pot Synthesis of Amphiphilic Linear and Hyperbranched Polyelectrolytes and Their Stimuli-Responsive Self-Assembly in Aqueous Solutions
    Gerardos, Angelica Maria
    Forys, Aleksander
    Trzebicka, Barbara
    Pispas, Stergios
    POLYMERS, 2025, 17 (05)
  • [50] Novel amphiphilic diblock copolymers bearing acid-labile oxazolidine moieties: Synthesis, self-assembly and responsive behavior in aqueous solution
    Cui, Qianling
    Wu, Feipeng
    Wang, Erjian
    POLYMER, 2011, 52 (08) : 1755 - 1765
12345