Copolymerization of Propylene Oxide and Carbon Dioxide

被引:9
作者
Narang, Shilpa [1 ]
Mehta, Rajeev [2 ]
Upadhyay, S. N. [3 ]
机构
[1] Thapar Univ, Sch Chem & Biochem, Patiala 147004, Punjab, India
[2] Thapar Univ, Dept Chem Engn, Patiala 147004, Punjab, India
[3] IIT BHU, Dept Chem Engn & Technol, Varanasi 221005, Uttar Pradesh, India
关键词
Copolymerization; CO2; sequestration; propylene oxide; poly(propylene carbonate); cyclic carbonate; catalysts; ALTERNATING COPOLYMERIZATION; EFFICIENT SYNTHESIS; CYCLIC CARBONATE; COBALT-PORPHYRIN; SALEN COMPLEXES; METAL-COMPLEXES; CO2; CATALYSTS; EPOXIDES; SYSTEM;
D O I
10.2174/1385272819666150803224204
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The alternating copolymerization of carbon dioxide and epoxides to give polycarbonates and cyclic carbonates has attracted the attention of researchers since it fixes CO2, a green house gas, chemically. This review makes an attempt to present a critical assessment of the available information particularly on copolymerization of propylene oxide and CO2 and thereby indicates the areas and gaps where further work is required. The efficacy of various inorganic, organometallic and ligand metal complexes has been thoroughly analyzed.
引用
收藏
页码:2344 / 2357
页数:14
相关论文
共 50 条
  • [21] Synthesis of biodegradable polycarbonate by alternating copolymerization of carbon dioxide and propylene oxide using a cobalt/Schiff base catalyst
    Li, Hongchun
    Niu, Yongsheng
    REACTIVE & FUNCTIONAL POLYMERS, 2011, 71 (02) : 121 - 125
  • [22] Study on Thermal Decomposition Behaviors of Terpolymers of Carbon Dioxide, Propylene Oxide, and Cyclohexene Oxide
    Chen, Shaoyun
    Xiao, Min
    Sun, Luyi
    Meng, Yuezhong
    INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2018, 19 (12)
  • [23] (Salan)CrCl, An Effective Catalyst for the Copolymerization and Terpolymerization of Epoxides and Carbon Dioxide
    Darensbourg, Donald J.
    Poland, Ross R.
    Strickland, Amanda L.
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2012, 50 (01) : 127 - 133
  • [24] Copolymerization of propylene oxide and carbon dioxide in the presence of diphenylmethane diisoyanate
    Jingshu Wu
    Min Xiao
    Hu He
    Shuanjin Wang
    Dongmei Han
    Yuezhong Meng
    Journal of Polymer Research, 2011, 18 : 1479 - 1486
  • [25] The Kinetics of Carbon Dioxide and Propylene Oxide Copolymerization Catalyzed by Binary Catalyst System
    Chukanova, O. M.
    Bukhovets, E. V.
    Perepelitsina, E. O.
    Belov, G. P.
    POLYMER SCIENCE SERIES B, 2015, 57 (03) : 224 - 227
  • [26] Copolymerization of Carbon Dioxide and Cyclohexene Oxide Catalyzed by Chromium Complexes Bearing Semirigid [ONSO]-Type Ligands
    Han, Bing
    Zhang, Li
    Kyran, Samuel J.
    Liu, Binyuan
    Duan, Zhongyu
    Darensbourg, Donald J.
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2016, 54 (13) : 1938 - 1944
  • [27] The Influence of Reagent Concentration on the Kinetics of Carbon Dioxide-Propylene Oxide Copolymerization in the Presence of a Cobalt Complex
    Chukanova, O. M.
    Perepelitsina, E. O.
    Belov, G. P.
    POLYMER SCIENCE SERIES B, 2014, 56 (05) : 547 - 552
  • [28] Bimetallic mechanism operating in the copolymerization of propylene oxide with carbon dioxide catalyzed by cobalt-salen complexes
    Nakano, Koji
    Hashimoto, Shinichi
    Nozaki, Kyoko
    CHEMICAL SCIENCE, 2010, 1 (03) : 369 - 373
  • [29] Copolymerisation of Propylene Oxide and Carbon Dioxide by Dinuclear Cobalt Porphyrins
    Anderson, Carly E.
    Vagin, Sergei I.
    Hammann, Markus
    Zimmermann, Leander
    Rieger, Bernhard
    CHEMCATCHEM, 2013, 5 (11) : 3269 - 3280
  • [30] Effect of the ligand nature in cobalt complexes on the selectivity of the reaction of carbon dioxide and propylene oxide
    Chukanova, O. M.
    Belov, G. P.
    KINETICS AND CATALYSIS, 2016, 57 (06) : 821 - 825